Introduction To Chemistry 5th Edition
Introduction To Chemistry 5th Edition
5th Edition
ISBN: 9781260162097
Author: BAUER
Publisher: MCG
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Chapter 9, Problem 118QP
Interpretation Introduction

Interpretation:

The volume of NO at STP is to be determined.

Concept Introduction:

Avogadro’s law gives a relationship at constant temperature and pressure between the volume of a gas and number of moles present in the gas. The volume of gas V is directly proportional to the number of moles n present in the gas at constant temperature and pressure.

VnV1n1=V2n2

Combined gas law is a law which is derived from the combination of Boyle’s law, Charles’ s law, and Gay-Lussac’s law. It states that the pressure P and the volume V of the gas are directly proportional to the temperature T of the gas.

P1V1T1=P2V2T2 …(1)

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Nitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?
Sodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?

Chapter 9 Solutions

Introduction To Chemistry 5th Edition

Ch. 9 - Prob. 6PPCh. 9 - Prob. 7PPCh. 9 - Prob. 8PPCh. 9 - Prob. 9PPCh. 9 - Prob. 10PPCh. 9 - Prob. 11PPCh. 9 - Prob. 12PPCh. 9 - Prob. 13PPCh. 9 - Prob. 14PPCh. 9 - Prob. 15PPCh. 9 - Prob. 16PPCh. 9 - Prob. 17PPCh. 9 - Prob. 18PPCh. 9 - Prob. 1QPCh. 9 - Prob. 2QPCh. 9 - Prob. 3QPCh. 9 - Prob. 4QPCh. 9 - A series of organic compounds called the alkanes...Ch. 9 - Prob. 6QPCh. 9 - Prob. 7QPCh. 9 - Prob. 8QPCh. 9 - Prob. 9QPCh. 9 - Prob. 10QPCh. 9 - Prob. 11QPCh. 9 - Prob. 12QPCh. 9 - Prob. 13QPCh. 9 - Prob. 14QPCh. 9 - Prob. 15QPCh. 9 - Prob. 16QPCh. 9 - Prob. 17QPCh. 9 - Prob. 18QPCh. 9 - Prob. 19QPCh. 9 - Prob. 20QPCh. 9 - Prob. 21QPCh. 9 - Prob. 22QPCh. 9 - Prob. 23QPCh. 9 - Prob. 24QPCh. 9 - Prob. 25QPCh. 9 - Prob. 26QPCh. 9 - Prob. 27QPCh. 9 - Prob. 28QPCh. 9 - Prob. 29QPCh. 9 - Prob. 30QPCh. 9 - Prob. 31QPCh. 9 - Prob. 32QPCh. 9 - Prob. 33QPCh. 9 - Prob. 34QPCh. 9 - Prob. 35QPCh. 9 - Prob. 36QPCh. 9 - Prob. 37QPCh. 9 - Prob. 38QPCh. 9 - Prob. 39QPCh. 9 - Prob. 40QPCh. 9 - Prob. 41QPCh. 9 - Prob. 42QPCh. 9 - Prob. 43QPCh. 9 - Prob. 44QPCh. 9 - Prob. 45QPCh. 9 - Prob. 46QPCh. 9 - Prob. 47QPCh. 9 - Prob. 48QPCh. 9 - Prob. 49QPCh. 9 - Prob. 50QPCh. 9 - Prob. 51QPCh. 9 - Prob. 52QPCh. 9 - Prob. 53QPCh. 9 - Prob. 54QPCh. 9 - Prob. 55QPCh. 9 - Prob. 56QPCh. 9 - Prob. 57QPCh. 9 - Prob. 58QPCh. 9 - Prob. 59QPCh. 9 - Prob. 60QPCh. 9 - Prob. 61QPCh. 9 - Prob. 62QPCh. 9 - Prob. 63QPCh. 9 - Prob. 64QPCh. 9 - Prob. 65QPCh. 9 - Prob. 66QPCh. 9 - Prob. 67QPCh. 9 - Prob. 68QPCh. 9 - Prob. 69QPCh. 9 - Prob. 70QPCh. 9 - Prob. 71QPCh. 9 - Prob. 72QPCh. 9 - Prob. 73QPCh. 9 - Prob. 74QPCh. 9 - Prob. 75QPCh. 9 - Prob. 76QPCh. 9 - Prob. 77QPCh. 9 - Prob. 78QPCh. 9 - Prob. 79QPCh. 9 - Prob. 80QPCh. 9 - Prob. 81QPCh. 9 - Prob. 82QPCh. 9 - Prob. 83QPCh. 9 - Prob. 84QPCh. 9 - Prob. 85QPCh. 9 - Prob. 86QPCh. 9 - Prob. 87QPCh. 9 - Prob. 88QPCh. 9 - Prob. 89QPCh. 9 - Prob. 90QPCh. 9 - Prob. 91QPCh. 9 - Prob. 92QPCh. 9 - Prob. 93QPCh. 9 - Prob. 94QPCh. 9 - Prob. 95QPCh. 9 - Prob. 96QPCh. 9 - Prob. 97QPCh. 9 - Prob. 98QPCh. 9 - Prob. 99QPCh. 9 - Prob. 100QPCh. 9 - Prob. 101QPCh. 9 - Prob. 102QPCh. 9 - Prob. 103QPCh. 9 - Prob. 104QPCh. 9 - Prob. 105QPCh. 9 - Prob. 106QPCh. 9 - Prob. 107QPCh. 9 - Prob. 108QPCh. 9 - Prob. 109QPCh. 9 - Prob. 110QPCh. 9 - Prob. 111QPCh. 9 - Prob. 112QPCh. 9 - Prob. 113QPCh. 9 - Prob. 114QPCh. 9 - Prob. 115QPCh. 9 - Prob. 116QPCh. 9 - Prob. 117QPCh. 9 - Prob. 118QPCh. 9 - Prob. 119QPCh. 9 - Prob. 120QPCh. 9 - Prob. 121QPCh. 9 - Prob. 122QPCh. 9 - Prob. 123QPCh. 9 - Prob. 124QPCh. 9 - Prob. 125QPCh. 9 - Prob. 126QPCh. 9 - Prob. 127QPCh. 9 - Prob. 128QPCh. 9 - Prob. 129QPCh. 9 - Prob. 130QPCh. 9 - Prob. 131QPCh. 9 - Prob. 132QPCh. 9 - Prob. 133QPCh. 9 - Prob. 134QPCh. 9 - Prob. 135QPCh. 9 - Prob. 136QPCh. 9 - Prob. 137QPCh. 9 - Prob. 138QPCh. 9 - Prob. 139QPCh. 9 - Prob. 140QPCh. 9 - Prob. 141QPCh. 9 - Prob. 142QPCh. 9 - Prob. 143QPCh. 9 - Prob. 144QPCh. 9 - Prob. 145QPCh. 9 - Prob. 146QPCh. 9 - Prob. 147QPCh. 9 - Prob. 148QPCh. 9 - Prob. 149QPCh. 9 - Prob. 150QPCh. 9 - Prob. 151QPCh. 9 - Prob. 152QPCh. 9 - Prob. 153QPCh. 9 - Prob. 154QPCh. 9 - Prob. 155QPCh. 9 - Prob. 156QPCh. 9 - Prob. 157QPCh. 9 - Prob. 158QPCh. 9 - Prob. 159QPCh. 9 - Prob. 160QPCh. 9 - Prob. 161QPCh. 9 - Prob. 162QPCh. 9 - Prob. 163QPCh. 9 - Prob. 164QPCh. 9 - Prob. 165QPCh. 9 - Butane burns with oxygen according to the...Ch. 9 - Prob. 167QP
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