Explanation The electron configuration of Ne having atomic number 10 is 1s 2 2 s 2 2 p 6 . Therefore, the total number of electrons present in Ne 2 molecule are 20 . Therefore, the electronic configuration of Ne 2 molecule is, ( σ 1s ) 2 ( σ 1 s ∗ ) 2 ( σ 2s ) 2 ( σ 2s ∗ ) 2 ( σ 2p z ) 2 ( π 2 p x ) 2 ( π 2 p y ) 2 ( π 2 p x ∗ ) 2 ( π 2 p y ∗ ) 2 ( σ 2p z ∗ ) 2 The bond order of Ne 2 is calculated by the formula, Bond order = 1 2 ( N b − N a ) Where, N b is the number of electrons present in bonding molecular orbital. N a is the number of electrons present in anti bonding molecular orbital. Substitute the value of 10 for N b and 10 for N a in the above formula as it has 10 electron in the bonding MO and 10 electrons in the antibonding molecular orbital. Bond order = 1 2 ( 10 − 10 ) = 0 Therefore, the bond order of Ne 2 molecule is 0 . The electron configuration of N having atomic number 7 is 1s 2 2 s 2 2 p 3 . Therefore, the total number of electrons present in N 2 + ion are 13 . Therefore, the electronic configuration of N 2 + molecule is, ( σ 1s ) 2 ( σ 1 s ∗ ) 2 ( σ 2s ) 2 ( σ 2s ∗ ) 2 ( π 2 p x ) 2 ( π 2 p y ) 2 ( σ 2p z ) 1 Therefore, the bond order of N 2 + ion is calculated by the formula, Bond order = 1 2 ( N b − N a ) Where, N b is the number of electrons present in bonding molecular orbital. N a is the number of electrons present in anti bonding molecular orbital. Substitute the value of 9 for N b and 4 for N a in the above formula as it has 9 electron in the bonding MO and 4 electrons in the antibonding molecular orbital. Bond order = 1 2 ( 9 − 4 ) = 5 2 = 2.5 Therefore, the bond order of N 2 + ion is 2.5 . The electron configuration of B having atomic number 5 is 1s 2 2 s 2 2 p 1 . Therefore, the total number of electrons present in B 2 molecule are 10 . Therefore, the electronic configuration of B 2 molecule is, ( σ 1s ) 2 ( σ 1 s ∗ ) 2 ( σ 2s ) 2 ( σ 2s ∗ ) 2 ( π 2 p x ) 1 ( π 2 p y ) 1 Therefore, the bond order of B 2 is calculated by the formula, Bond order = 1 2 ( N b − N a ) Where, N b is the number of electrons present in bonding molecular orbital

Chemistry: The Central Science (14th Edition)

14th Edition

ISBN: 9780134414232

Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus

Publisher: PEARSON

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Chapter 9, Problem 106AE

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To determine: The arrangement of the given molecules and ions from smallest to the largest bond order.

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Chapter 9, Problem 105AE

Chapter 9, Problem 107AE

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Chapter 9 Solutions

Chemistry: The Central Science (14th Edition)

Ch. 9.2 - Consider the following AB3 molecules and ions-...Ch. 9.2 - Prob. 9.1.2PE Ch. 9.2 - Prob. 9.2.1PE Ch. 9.2 - Prob. 9.2.2PE Ch. 9.2 - Prob. 9.3.1PE Ch. 9.2 - Prob. 9.3.2PE Ch. 9.3 - Prob. 9.4.1PE Ch. 9.3 - Determine whether the following molecules are...Ch. 9.5 - Prob. 9.5.1PE Ch. 9.5 - Prob. 9.5.2PE

Ch. 9.6 - Prob. 9.6.1PE Ch. 9.6 - Prob. 9.6.2PE Ch. 9.6 - Prob. 9.7.1PE Ch. 9.6 - Prob. 9.7.2PE Ch. 9.7 - Prob. 9.8.1PE Ch. 9.7 - Prob. 9.8.2PE Ch. 9.8 - Prob. 9.9.1PE Ch. 9.8 - Prob. 9.9.2PE Ch. 9 - Prob. 1DE Ch. 9 - 9.1 A certain AB4, molecule has a "seesaw" shape...Ch. 9 - Prob. 2E Ch. 9 - Prob. 3E Ch. 9 - Prob. 4E Ch. 9 - Prob. 5E Ch. 9 - Prob. 6E Ch. 9 - In the hydrocarbon a. What is the hybridization at...Ch. 9 - The drawing below shows the overlap of two hybrid...Ch. 9 - Prob. 9E Ch. 9 - 9.10 The following is part of a molecular...Ch. 9 - Prob. 11E Ch. 9 - Prob. 12E Ch. 9 - 9.13 a. An AB2 molecule is linear. How...Ch. 9 - a. Methane (CH4) and the perchlorate ion (C104-)...Ch. 9 - Prob. 15E Ch. 9 - Prob. 16E Ch. 9 - Prob. 17E Ch. 9 - Prob. 18E Ch. 9 - In which of these molecules or ions does the...Ch. 9 - Prob. 20E Ch. 9 - How many nonbonding electron pairs are there in...Ch. 9 - Prob. 22E Ch. 9 - Prob. 23E Ch. 9 - Prob. 24E Ch. 9 - Give the electron-domain and molecular geometries...Ch. 9 - Prob. 26E Ch. 9 - Prob. 27E Ch. 9 - Prob. 28E Ch. 9 - Prob. 29E Ch. 9 - Prob. 30E Ch. 9 - Ammonia, NH3 reacts with incredibly strong bases...Ch. 9 - In which of the following AFn molecules or ions is...Ch. 9 - a. Explain why BrF4 is square planar, whereas...Ch. 9 - 9.34 Name the proper three-dimensional molecule...Ch. 9 - Prob. 35E Ch. 9 - Prob. 36E Ch. 9 - Prob. 37E Ch. 9 - Prob. 38E Ch. 9 - a. (a) Is the molecule BF3 polar or nonpolar? b....Ch. 9 - Prob. 40E Ch. 9 - Predict whether each of the following molecules is...Ch. 9 - Prob. 42E Ch. 9 - Prob. 43E Ch. 9 - Prob. 44E Ch. 9 - For each statement, irldicate whether it is true...Ch. 9 - Draw sketches illustrating the overlap between the...Ch. 9 - For each statement, indicate whether it is true or...Ch. 9 - Prob. 48E Ch. 9 - Prob. 49E Ch. 9 - Consider the SC12 molecule. a. What IS the...Ch. 9 - Indicate the hybridization of the central atom in...Ch. 9 - Prob. 52E Ch. 9 - Prob. 53E Ch. 9 - Prob. 54E Ch. 9 - Prob. 55E Ch. 9 - Prob. 56E Ch. 9 - a. Draw Lewis structures for ethane (C2He),...Ch. 9 - a. Draw Lewis structures for ethane (C2He),...Ch. 9 - Prob. 59E Ch. 9 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 9 - Prob. 61E Ch. 9 - Prob. 62E Ch. 9 - Prob. 63E Ch. 9 - Prob. 64E Ch. 9 - In the formate ion, HC02- , the carbon atom is the...Ch. 9 - Prob. 66E Ch. 9 - Prob. 67E Ch. 9 - Prob. 68E Ch. 9 - Prob. 69E Ch. 9 - a. If you combine two atomic orbitals on two...Ch. 9 - Prob. 71E Ch. 9 - Prob. 72E Ch. 9 - Prob. 73E Ch. 9 - Indicate whether each statement is true or false....Ch. 9 - Prob. 75E Ch. 9 - Prob. 76E Ch. 9 - Prob. 77E Ch. 9 - Prob. 78E Ch. 9 - Prob. 79E Ch. 9 - Prob. 80E Ch. 9 - Determine the electron configurations for CN+, CN,...Ch. 9 - Prob. 82E Ch. 9 - Consider the molecular orbitals of the P2...Ch. 9 - The iodine bromide molecule, IBr, is an...Ch. 9 - Prob. 85AE Ch. 9 - Prob. 86AE Ch. 9 - Consider the following XF4 ions: PF4, BrF4-,...Ch. 9 - 9.88 Consider the molecule PF4Cl....Ch. 9 - Prob. 89AE Ch. 9 - Fill in the blank spaces in the following chart....Ch. 9 - Prob. 91AE Ch. 9 - Prob. 92AE Ch. 9 - Prob. 93AE Ch. 9 - Prob. 94AE Ch. 9 - Prob. 95AE Ch. 9 - Prob. 96AE Ch. 9 - Prob. 97AE Ch. 9 - Prob. 98AE Ch. 9 - Prob. 99AE Ch. 9 - Prob. 100AE Ch. 9 - In ozone, 03, the two oxygen atoms on the ends Of...Ch. 9 - Butadiene, C4H6, is a planar molecule that has the...Ch. 9 - The structure of borazine, B3N3H6, is a...Ch. 9 - Prob. 104AE Ch. 9 - Prob. 105AE Ch. 9 - Prob. 106AE Ch. 9 - Prob. 107AE Ch. 9 - Prob. 108AE Ch. 9 - Azo dyes are organic dyes that are used for many...Ch. 9 - a. Using only the valence atomic orbitals of a...Ch. 9 - Carbon monoxide, CO, is isoelectronic to N2. a....Ch. 9 - The energy-level diagram in Figure 9.36 shows that...Ch. 9 - A compound composed of 2.1 29.8%N, and 68.1%O has...Ch. 9 - 9.114 Sulfur tetrafluoride (SR4) reacts slowly...Ch. 9 - Prob. 115IE Ch. 9 - The molecule 2-butene, C4Hs, can undergo a...Ch. 9 - Prob. 117IE Ch. 9 - Use average bond enthalpies (Table 8.3 ) to...Ch. 9 - Prob. 119IE Ch. 9 - Prob. 120IE Ch. 9 - Prob. 121IE Ch. 9 - Prob. 122IE

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