a) Interpretation: The structures of alkenes that would yield the alcohol shown on hydration are to be given. Among hydroboration-oxidation and oxymercuration-demercuration, which method could be used to prepare the alcohol also has to be stated. Concept introduction: The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the carbon with less number of alkyl substitutents. The oxymercuration-demercuration reaction takes place with anti stereochemistry and results in Markovnokov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the carbon with more number of alkyl substitutents. To give: The structures of alkenes that would yield the alcohol shown on hydration. To state: Among hydroboration-oxidation and oxymercuration-demercuration methods which method can be used to prepare the alcohol from alkenes.

Question

please help and i am so confused if the picture is the gc data or ir spectrum. you dont have to do everything just what you can please because i am lost and the mass of the cloves was Mass of cloves 62.299g. Mass of recovered clove oil 62.761g.

Answer 1

Question

Chapter 8.SE, Problem 23VC

Interpretation Introduction

a)

Interpretation:

The structures of alkenes that would yield the alcohol shown on hydration are to be given. Among hydroboration-oxidation and oxymercuration-demercuration, which method could be used to prepare the alcohol also has to be stated.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the carbon with less number of alkyl substitutents.

The oxymercuration-demercuration reaction takes place with anti stereochemistry and results in Markovnokov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the carbon with more number of alkyl substitutents.

To give:

The structures of alkenes that would yield the alcohol shown on hydration.

To state:

Among hydroboration-oxidation and oxymercuration-demercuration methods which method can be used to prepare the alcohol from alkenes.

Interpretation Introduction

b)

Interpretation:

The structures of alkenes that would yield the alcohol shown on hydration are to be given. Among hydroboration-oxidation and oxymercuration-demercuration, the method which can be used to prepare the alcohol also has to be stated.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the carbon with less number of alkyl substitutents.

The oxymercuration-demercuration reaction takes place with anti stereochemistry and results in Markovnokov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the carbon with more number of alkyl substitutents.

To give:

The structures of alkenes that would yield the alcohol shown on hydration.

To state:

Among hydroboration-oxidation and oxymercuration-demercuration, the method which can be used to prepare the alcohol.

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