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Chapter 8.7, Problem 13P
Interpretation Introduction

Interpretation:

The product, with its stereochemistry, obtained when cis-2-butene reacts with meta-chloroperoxybenzoic acid is to be given.

Concept introduction:

Alkenes are oxidized to give epoxides or oxiranes when treated with peracids like meta-chloroperoxybenzoic acid. The oxygen transfer from the peroxy acids takes place with syn stereochemistry. Both the C-O bonds are formed from the same face of the double bond through a one step process without the formation of an intermediate. The oxygen atom farthest from the carbonyl group gets transferred.

To give:

The product, with its stereochemistry, obtained when cis-2-butene reacts with meta-chloroperoxybenzoic acid.

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Chapter 8 Solutions

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