a) Interpretation: The product expected from oxymercuration-demercuration of 1-pentene is to be given. Concept introduction: In the oxymercuration-demercuration process, in the first step, the electrophilic addition of Hg 2+ to the double bond in alkene takes place to give a mercurinium ion. In the next step the mercurinium ion reacts with water to yield an organomercury product. In the last step, NaBH 4 removes mercury from the organomercury product to give a more highly substituted alcohol, corresponding to Markovnikov regiochemistry, as the product. To give: The product expected from oxymercuration-demercuration of 1-pentene.

Question

Place the following characteristics into the box for the correct ion. Note that some of the characteristics will not be placed in either bin. Use your periodic table for assistance. Link to Periodic Table Drag the characteristics to their respective bins. ▸ View Available Hint(s) This anion could form a neutral compound by forming an ionic bond with one Ca²+. Reset Help This ion forms ionic bonds with nonmetals. This ion has a 1- charge. This is a polyatomic ion. The neutral atom from which this ion is formed is a metal. The atom from which this ion is formed gains an electron to become an ion. The atom from which this ion is formed loses an electron to become an ion. This ion has a total of 18 electrons. This ion has a total of 36 electrons. This ion has covalent bonds and a net 2- charge. This ion has a 1+ charge. Potassium ion Bromide ion Sulfate ion

Answer 1

Question

Chapter 8.4, Problem 7P

Interpretation Introduction

a)

Interpretation:

The product expected from oxymercuration-demercuration of 1-pentene is to be given.

Concept introduction:

In the oxymercuration-demercuration process, in the first step, the electrophilic addition of Hg²⁺ to the double bond in alkene takes place to give a mercurinium ion. In the next step the mercurinium ion reacts with water to yield an organomercury product. In the last step, NaBH₄ removes mercury from the organomercury product to give a more highly substituted alcohol, corresponding to Markovnikov regiochemistry, as the product.

To give:

The product expected from oxymercuration-demercuration of 1-pentene.

Interpretation Introduction

b)

Interpretation:

The product expected from oxymercuration-demercuration of 2-methyl-2-pentene is to be given.

Concept introduction:

In the oxymercuration-demercuration process, in the first step, the electrophilic addition of Hg²⁺ to the alkene takes place to give a mercurinium ion. In the next step, the mercurinium ion reacts with water to yield an organomercury product. In the last step, reaction with NaBH₄ removes mercury from the organomercury product to give a more highly substituted alcohol, corresponding to Markovnikov regiochemistry, as the product.

To give:

The product expected from oxymercuration-demercuration of 2-methyl-2-pentene.

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