EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 8.5, Problem 4E

(a)

Interpretation Introduction

Interpretation:- The products formed by assigning the appropriate mass spectrum to each compound needs to be confirmed. The parent and the base peaks needs to be specified.

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  1

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  2

Fig − 8.61

Mass spectrum of component of reaction mixture

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  3

Fig − 8.62

Mass spectrum of component of reaction mixture

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  4

Fig − 8.63

Mass spectrum of component of reaction mixture

Concept Introduction: Fragmentation is the process in which energetically unstable molecular ions gets dissociated, when these molecules are passed through the ionization chamber of a mass spectrometer.

(b)

Interpretation Introduction

Interpretation:- The compound represented by the mass spectrum needs to be identified.

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  5

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  6

Fig − 8.61

Mass spectrum of component of reaction mixture

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  7

Fig − 8.62

Mass spectrum of component of reaction mixture

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  8

Fig − 8.63

Mass spectrum of component of reaction mixture

Concept Introduction: Fragmentation is the process in which energetically unstable molecular ions gets dissociated, when these molecules are passed through the ionization chamber of a mass spectrometer.

(c)

Interpretation Introduction

Interpretation: The structure of the ion for each of the peaks for which value of mz is provided needs to be predicted.

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  9

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  10

Fig − 8.61

Mass spectrum of component of reaction mixture

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  11

Fig − 8.62

Mass spectrum of component of reaction mixture

  EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M, Chapter 8.5, Problem 4E , additional homework tip  12

Fig − 8.63

Mass spectrum of component of reaction mixture

Concept Introduction: Fragmentation is the process in which energetically unstable molecular ions gets dissociated, when these molecules are passed through the ionization chamber of a mass spectrometer.

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