EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 8.3, Problem 7E

(a)

Interpretation Introduction

Interpretation:

The relative and absolute ratios of different hydrogens in pair of compounds needs to be determined.

Concept Introduction :

By using hydrogen NMR, it is possible to determine the number of hydrogens in each molecule which gives only the relative number of hydrogens and not the absolute. The peaks obtained from the H-NMR indicates that either there is one hydrogen, or more than 2 hydrogens based on the size of the peak but it cannot determine how many hydrogens. For which the ratio is to eb compared to determine the absolute hydrogen.

(b)

Interpretation Introduction

Interpretation:

The relative and absolute ratios of different hydrogens in pair of compounds needs to be determined.

Concept Introduction :

By using hydrogen NMR, it is possible to determine how many hydrogens in each molecule which gives only the relative number of hydrogens and not the absolute. The peaks obtained from the H-NMR indicates that either there is one hydrogen, or more than 2 hydrogens based on the size of the peak, but it cannot determine how many hydrogens. For which the ratio is to be compared to determine the absolute hydrogen.

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4. Halogenated compounds are particularly easy to identify by their mass spectra because chlorine and bromine occur naturally as mixtures of two abundant isotopes. Chlorine occurs as "CI (75.8%) and "CI (24.2%). Ignore the presence of "C isotopes. For the compound, C,H,Cl;: a) At what masses do the molecular ions occur? b)What are the percentages of cach molecular ion?
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