Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 8.4, Problem 8.16P
Calculate the value of [OH−] from the given [H3O+] in each solution and label the solution as acidic or basic: (a) [H3O+] = 10−3 M; (b) [H3O+] = 10−11 M; (c) [H3O+] = 2.8 × 10−10 M; (d) [H3O+] = 5.6 × 10−4 M.
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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Chapter 8 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 8.1 - Name each acid: (a) HF; (b) HNO3; (c) HCN.Ch. 8.1 - Prob. 8.2PCh. 8.1 - Which of the following species can be BrnstedLowry...Ch. 8.1 - Which of the following species can be BrnstedLowry...Ch. 8.1 - Classify each reactant as a BrnstedLowry acid or...Ch. 8.2 - Draw the conjugate acid of each species: (a) H2O;...Ch. 8.2 - Draw the conjugate base of each species: (a) H2S;...Ch. 8.2 - Draw the structure of the conjugate base of each...Ch. 8.2 - Label the acid and the base and the conjugate acid...Ch. 8.2 - Ammonia, NH3, is amphoteric. (a) Draw the...
Ch. 8.2 - When ascorbic acid (vitamin C, molecular formula...Ch. 8.3 - Prob. 8.12PCh. 8.3 - Prob. 8.13PCh. 8.3 - Prob. 8.14PCh. 8.3 - Prob. 8.15PCh. 8.4 - Calculate the value of [OH] from the given [H3O+]...Ch. 8.4 - Calculate the value of [H3O+] from the given [OH]...Ch. 8.4 - Calculate the value of [H3O+] and [OH] in each...Ch. 8.5 - Convert each H3O+ concentration to a pH value. a....Ch. 8.5 - What H3O+ concentration corresponds to each pH...Ch. 8.5 - Prob. 8.21PCh. 8.5 - Prob. 8.22PCh. 8.6 - Write a balanced equation for each acidbase...Ch. 8.6 - Prob. 8.24PCh. 8.6 - Prob. 8.25PCh. 8.6 - Write a balanced equation for the reaction of...Ch. 8.7 - Prob. 8.27PCh. 8.7 - Prob. 8.28PCh. 8.8 - Prob. 8.29PCh. 8.8 - Prob. 8.30PCh. 8 - Draw the structure of the conjugate base of each...Ch. 8 - Draw the structure of the conjugate base of each...Ch. 8 - (a) Which of the following represents a strong...Ch. 8 - Prob. 8.34UKCCh. 8 - Identify the acid, base, conjugate acid, and...Ch. 8 - Prob. 8.36UKCCh. 8 - Prob. 8.37UKCCh. 8 - Prob. 8.38UKCCh. 8 - Prob. 8.39UKCCh. 8 - Prob. 8.40UKCCh. 8 - If a urine sample has a pH of 5.90, calculate the...Ch. 8 - Prob. 8.42UKCCh. 8 - Prob. 8.43UKCCh. 8 - Prob. 8.44UKCCh. 8 - Consider a buffer prepared from the weak acid HNO2...Ch. 8 - Prob. 8.46UKCCh. 8 - Prob. 8.47APCh. 8 - Prob. 8.48APCh. 8 - Prob. 8.49APCh. 8 - Prob. 8.50APCh. 8 - Prob. 8.51APCh. 8 - Prob. 8.52APCh. 8 - Draw the conjugate base of each acid. a. HNO2 b....Ch. 8 - Draw the conjugate base of each acid. a. H3O+ b....Ch. 8 - Prob. 8.55APCh. 8 - Prob. 8.56APCh. 8 - Prob. 8.57APCh. 8 - Like H2O, H2PO4 is amphoteric. (a) Draw the...Ch. 8 - Prob. 8.59APCh. 8 - Prob. 8.60APCh. 8 - Prob. 8.61APCh. 8 - Prob. 8.62APCh. 8 - Prob. 8.63APCh. 8 - Prob. 8.64APCh. 8 - Prob. 8.65APCh. 8 - Prob. 8.66APCh. 8 - Prob. 8.67APCh. 8 - Prob. 8.68APCh. 8 - Calculate the value of [OH] from the given [H3O+]...Ch. 8 - Calculate the value of [OH] from the given [H3O+]...Ch. 8 - Calculate the value of [H3O+] from the given [OH]...Ch. 8 - Prob. 8.72APCh. 8 - Prob. 8.73APCh. 8 - Calculate the pH from each H3O+ concentration...Ch. 8 - Prob. 8.75APCh. 8 - Prob. 8.76APCh. 8 - What are the concentrations of H3O+ and OH in...Ch. 8 - Prob. 8.78APCh. 8 - Prob. 8.79APCh. 8 - Prob. 8.80APCh. 8 - Prob. 8.81APCh. 8 - Prob. 8.82APCh. 8 - Prob. 8.83APCh. 8 - Prob. 8.84APCh. 8 - Prob. 8.85APCh. 8 - Prob. 8.86APCh. 8 - Prob. 8.87APCh. 8 - Prob. 8.88APCh. 8 - Consider a weak acid H2A and its conjugate base...Ch. 8 - Consider a weak acid H2A and its conjugate base...Ch. 8 - Prob. 8.91APCh. 8 - Prob. 8.92APCh. 8 - Prob. 8.93APCh. 8 - Prob. 8.94APCh. 8 - The optimum pH of a swimming pool is 7.50....Ch. 8 - A sample of rainwater has a pH of 4.18. (a)...Ch. 8 - Prob. 8.97APCh. 8 - Prob. 8.98APCh. 8 - Prob. 8.99APCh. 8 - Explain why a lake on a bed of limestone is...Ch. 8 - Prob. 8.101CP
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