Organic Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (9th Edition) (New in Organic Chemistry)

9th Edition

ISBN: 9780321971128

Author: Leroy G. Wade, Jan W. Simek

Publisher: PEARSON

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Aromatic Compounds

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Textbook Question

Chapter 8.13, Problem 8.30P

a. Propose a mechanism for the conversion of cis-hex-3-ene to the epoxide (3,4-epoxyhexane) and the ring-opening reaction to give the glycol, hexane 3,4-diol. In your mechanism, pay particular attention to the stereochemistry of the intermediates and products.
b. Repeat part (a) for trans-hex-3-ene. Compare the products obtained from cis- and trans-hex-3-ene. Is this reaction sequence stereospecific?

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Chapter 8.12, Problem 8.29P

Chapter 8.13, Problem 8.31P

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Chapter 8 Solutions

Organic Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (9th Edition) (New in Organic Chemistry)

Ch. 8.3A - Predict the major products of the following...Ch. 8.3A - a. When 1 mole of buta-1,3-diene reacts with 1...Ch. 8.3B - Predict the major products of the following...Ch. 8.3B - Show how you would accomplish the following...Ch. 8.4B - Propose a mechanism to show how...Ch. 8.4B - Predict the products of the following hydration...Ch. 8.6 - a. Propose a mochansm fortho following reaction....Ch. 8.6 - Prob. 8.8P Ch. 8.6 - Prob. 8.9P Ch. 8.7A - Prob. 8.10P

Ch. 8.7A - Prob. 8.11P Ch. 8.7C - Prob. 8.12P Ch. 8.7C - Prob. 8.13P Ch. 8.7C - a. When (Z)-3-methylhex-3-ene undergoes...Ch. 8.7C - Prob. 8.15P Ch. 8.7C - Prob. 8.16P Ch. 8.8B - Prob. 8.17P Ch. 8.8B - Prob. 8.18P Ch. 8.9 - Prob. 8.19P Ch. 8.9 - Prob. 8.20P Ch. 8.9 - Prob. 8.21P Ch. 8.9 - Prob. 8.22P Ch. 8.10 - Prob. 8.23P Ch. 8.10 - Prob. 8.24P Ch. 8.10 - Prob. 8.25P Ch. 8.11A - Prob. 8.26P Ch. 8.11B - Prob. 8.27P Ch. 8.11B - Prob. 8.28P Ch. 8.12 - Prob. 8.29P Ch. 8.13 - a. Propose a mechanism for the conversion of...Ch. 8.13 - Magnesium monoperoxyphthalate (MMPP) epoxidizes...Ch. 8.13 - Predict the major products of the following...Ch. 8.13 - When 1,2-epoxycyclohexane (cyclohexene oxide) is...Ch. 8.14C - Predict the major products of the following...Ch. 8.14C - Prob. 8.35P Ch. 8.15B - Prob. 8.36P Ch. 8.15C - Predict the major products of the following...Ch. 8.16A - Prob. 8.38P Ch. 8.16A - Prob. 8.39P Ch. 8.16B - Prob. 8.40P Ch. 8.16B - Prob. 8.41P Ch. 8.16C - Prob. 8.42P Ch. 8.17B - Prob. 8.43P Ch. 8.17B - Prob. 8.44P Ch. 8.17B - Show how you would synthesize each compound,...Ch. 8 - Prob. 8.46SP Ch. 8 - Prob. 8.47SP Ch. 8 - Give the products expected when the following...Ch. 8 - Show how you would make the following compounds...Ch. 8 - Using 1,2-dimethylcyclohexene as your starting...Ch. 8 - Show how you would synthesize each compound using...Ch. 8 - Prob. 8.52SP Ch. 8 - Show how you might use olefin metathesis to...Ch. 8 - Prob. 8.54SP Ch. 8 - Prob. 8.55SP Ch. 8 - Propose mechanisms consistent with the following...Ch. 8 - Prob. 8.57SP Ch. 8 - Prob. 8.58SP Ch. 8 - Draw a reaction-energy diagram for the propagation...Ch. 8 - Prob. 8.60SP Ch. 8 - Prob. 8.61SP Ch. 8 - Prob. 8.62SP Ch. 8 - Prob. 8.63SP Ch. 8 - Prob. 8.64SP Ch. 8 - Prob. 8.65SP Ch. 8 - Prob. 8.66SP Ch. 8 - Prob. 8.67SP Ch. 8 - Prob. 8.68SP Ch. 8 - Prob. 8.69SP Ch. 8 - Prob. 8.70SP Ch. 8 - Prob. 8.71SP Ch. 8 - Prob. 8.72SP Ch. 8 - Prob. 8.73SP Ch. 8 - Prob. 8.74SP Ch. 8 - Prob. 8.75SP Ch. 8 - Prob. 8.76SP Ch. 8 - Prob. 8.77SP Ch. 8 - Prob. 8.78SP Ch. 8 - Prob. 8.79SP

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