The two organic products that are generated when the trialkylborane is oxidized with H 2 O 2 / NaOH . Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H 2 O 2 / NaOH and the structure of diene is to be stated. Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule. Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 1

Question

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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What I Have Learned Directions: Given the following reaction and the stress applied in each reaction, answer the question below. A. H2(g) + Cl2(g) 2 HCl(g) Stress applied: Decreasing the pressure 1. What is the Keq expression? 2. What will be the effect in the number of moles of HCl(g)? 3. What will be the Equilibrium Shift or the reaction? B. Fe3O4(s) + 4 H2(g) + heat 53 Fe(s) + 4 H₂O(g) Stress applied: Increasing the temperature 1. What is the Keq expression?. 2. What will be the effect in the volume of water vapor collected? 3. What will be the Equilibrium Shift or the reaction? C. 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g) + heat Stress applied: Increasing the volume of the container 1. What is the Keq expression?. 2. What will be the effect in the amount of H₂O? 3. What will be the Equilibrium Shift or the reaction?

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Q1: a) Arrange the compounds in order of decreasing pKa, highest first. ОН ΟΗ ῸΗ дон ОН ОН CI Br

Answer 2

Question

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 3

Question

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 4

Question

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 5

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 6

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 7

Chapter 8, Problem 8.79SP

(a)

Interpretation Introduction

To determine: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH.

Interpretation: The two organic products that are generated when the trialkylborane is oxidized with H2O2/NaOH and the structure of diene is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 8

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 9

(b)

Interpretation Introduction

To determine: The structure of the diene across which addition of BH3 synthesizes 9−BBM.

Interpretation: The structure of the diene across which addition of BH3 synthesises 9−BBM is to be drawn.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti markovinokov’s rule states that the positive part of halogen acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of halogen acid will get attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 10

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Answer 13

Ch. 8.3A - Predict the major products of the following...Ch. 8.3A - a. When 1 mole of buta-1,3-diene reacts with 1...Ch. 8.3B - Predict the major products of the following...Ch. 8.3B - Show how you would accomplish the following...Ch. 8.4B - Propose a mechanism to show how...Ch. 8.4B - Predict the products of the following hydration...Ch. 8.6 - a. Propose a mochansm fortho following reaction....Ch. 8.6 - Prob. 8.8P Ch. 8.6 - Prob. 8.9P Ch. 8.7A - Prob. 8.10P

Solution Summary: The author explains the hydroboration reaction, which involves conversion of alkene into alcohol, and the structure of diene.

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