Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Textbook Question
Chapter 8.1, Problem 8.5YT
Answer the following questions for solids, liquids, and gases. Provide an example to support each of your answers.
- a. Does it have a definite volume?
- b. Does it have a definite shape?
- c. Will it take the shape of its container?
- d. Will it completely fill its container?
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
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1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
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1.4M in both HF and NaF.
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
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Chapter 8 Solutions
Chemistry In Context
Ch. 8.1 - Answer the following questions for solids,...Ch. 8.1 - Prob. 8.6YTCh. 8.2 - Prob. 8.7YTCh. 8.2 - Prob. 8.8YTCh. 8.3 - Prob. 8.9YTCh. 8.3 - Prob. 8.10YTCh. 8.3 - Prob. 8.11YTCh. 8.3 - Prob. 8.12YTCh. 8.4 - Prob. 8.15YTCh. 8.4 - Prob. 8.16YT
Ch. 8.4 - Prob. 8.18YTCh. 8.4 - Prob. 8.19YTCh. 8.5 - Identify a recent drought or flood that caused...Ch. 8.5 - Prob. 8.22YTCh. 8.6 - Prob. 8.25YTCh. 8.6 - Prob. 8.26YTCh. 8.6 - Prob. 8.28YTCh. 8.7 - Prob. 8.30YTCh. 8.7 - Prob. 8.31YTCh. 8.7 - Prob. 8.32YTCh. 8.7 - Prob. 8.33YTCh. 8.7 - Prob. 8.35YTCh. 8.7 - Prob. 8.36YTCh. 8.8 - For each of the strong acids shown below, write a...Ch. 8.8 - Although the word acid may conjure up all sorts of...Ch. 8.8 - Prob. 8.39YTCh. 8.9 - For each acidbase pair, write a balanced...Ch. 8.9 - Prob. 8.42YTCh. 8.9 - Prob. 8.43YTCh. 8.10 - Skill Building Small Changes, Big Effects Compare...Ch. 8.10 - Prob. 8.47YTCh. 8.10 - Prob. 8.48YTCh. 8.11 - In 2008, a group of scientists met in Monaco to...Ch. 8.11 - Prob. 8.50YTCh. 8.12 - Skill Building Water Treatment Chemicals a. Write...Ch. 8.12 - Prob. 8.52YTCh. 8.12 - Prob. 8.53YTCh. 8.12 - Prob. 8.54YTCh. 8.12 - Prob. 8.55YTCh. 8.13 - Prob. 8.56YTCh. 8.13 - Prob. 8.57YTCh. 8.13 - Prob. 8.58YTCh. 8.13 - Prob. 8.59YTCh. 8 - Your Turn 8.1 You Decide Opposites Attract Examine...Ch. 8 - Prob. 8.2YTCh. 8 - In any language, water is the most abundant...Ch. 8 - Prob. 2QCh. 8 - Prob. 3QCh. 8 - Prob. 4QCh. 8 - The following are four pairs of atoms. Consult...Ch. 8 - Prob. 6QCh. 8 - Prob. 7QCh. 8 - Both methane (CH4) and water are compounds of...Ch. 8 - Prob. 9QCh. 8 - Prob. 10QCh. 8 - a. Draw the Lewis structure for the water...Ch. 8 - Prob. 12QCh. 8 - Prob. 13QCh. 8 - Prob. 14QCh. 8 - Based on your experience, how soluble is each of...Ch. 8 - Prob. 16QCh. 8 - NaCl is an ionic compound, but SiCl4 is a...Ch. 8 - Prob. 18QCh. 8 - Prob. 19QCh. 8 - Prob. 20QCh. 8 - Prob. 21QCh. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - For a 2.5 M solution of Mg(NO3)2, what is the...Ch. 8 - Prob. 25QCh. 8 - Prob. 26QCh. 8 - Classify the following aqueous solutions as...Ch. 8 - Prob. 28QCh. 8 - In each pair below, the [H+] is different. By what...Ch. 8 - Which of these has the lowest concentration of...Ch. 8 - Consider these ions: nitrate, sulfate, carbonate,...Ch. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - Prob. 34QCh. 8 - Which gas is dissolved in water to produce each of...Ch. 8 - Prob. 36QCh. 8 - Prob. 37QCh. 8 - Prob. 38QCh. 8 - Use the Internet to determine which has the higher...Ch. 8 - Prob. 40QCh. 8 - Prob. 41QCh. 8 - Prob. 42QCh. 8 - At the edge of a favorite fishing hole, a new sign...Ch. 8 - Prob. 44QCh. 8 - A diatomic molecule XY that contains a polar bond...Ch. 8 - Prob. 46QCh. 8 - Prob. 47QCh. 8 - Prob. 48QCh. 8 - Prob. 49QCh. 8 - The unusually high specific heat of water helps...Ch. 8 - Prob. 51QCh. 8 - Prob. 52QCh. 8 - Prob. 53QCh. 8 - Prob. 55QCh. 8 - In 2005, the Great LakesSt. Lawrence River Basin...Ch. 8 - Liquid CO2 has been used successfully for many...Ch. 8 - Prob. 58QCh. 8 - Prob. 60QCh. 8 - Prob. 61QCh. 8 - Hard water may contain Mg2+ and Ca2+ ions. The...Ch. 8 - Suppose you are in charge of regulating an...Ch. 8 - Prob. 64QCh. 8 - Prob. 65QCh. 8 - Prob. 66QCh. 8 - Prob. 67QCh. 8 - List a recent theme for World Water Day. Prepare a...Ch. 8 - Prob. 69Q
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