Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 8.1, Problem 8.2PP
Use the kinetic molecular theory of gases to explain each of the following:
- A container of nonstick cooking spray explodes when thrown into a fire.
- The air in a hot-air balloon is heated to make the balloon rise.
- You can smell the odor of cooking onions from far away.
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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment?
a) the heat capacity of the calorimeter
b) Mass of sample
c) Ti
d) The molarity of the HCl
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Chapter 8 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 8.1 - Prob. 8.1PPCh. 8.1 - Use the kinetic molecular theory of gases to...Ch. 8.1 - Identify the property of a gas that is measured in...Ch. 8.1 - Identify the property of a gas that is measured in...Ch. 8.1 - Prob. 8.5PPCh. 8.1 - Prob. 8.6PPCh. 8.1 - Prob. 8.7PPCh. 8.1 - On a climb up Mount Whitney, the atmospheric...Ch. 8.2 - Why do scuba divers need to exhale air when they...Ch. 8.2 - Why does a sealed bag of chips expand when you...
Ch. 8.2 - The air in a cylinder with a piston has a volume...Ch. 8.2 - A balloon is filled with helium gas. When each of...Ch. 8.2 - Prob. 8.13PPCh. 8.2 - Prob. 8.14PPCh. 8.2 - A 10.0-L balloon contains helium gas at a pressure...Ch. 8.2 - Prob. 8.16PPCh. 8.2 - A sample of nitrogen N2 has a volume of 50.0 L at...Ch. 8.2 - A sample of methane CH4 has a volume of 25 mL at a...Ch. 8.2 - A sample of Ar gas has a volume of 5.40 L with an...Ch. 8.2 - A sample of Ne gas has a pressure of 654 mmHg with...Ch. 8.2 - Prob. 8.21PPCh. 8.2 - A patient’s oxygen tank holds 20.0 L of oxygen O2...Ch. 8.2 - Prob. 8.23PPCh. 8.2 - Prob. 8.24PPCh. 8.3 - Select the diagram that shows the final volume of...Ch. 8.3 - Indicate whether the final volume of gas in each...Ch. 8.3 - A sample of neon initially has a volume of 2.50 L...Ch. 8.3 - Prob. 8.28PPCh. 8.3 - A balloon contains 2500 ml- of helium gas at 75C ....Ch. 8.3 - Prob. 8.30PPCh. 8.3 - A gas sample has a volume of 0.256 L with an...Ch. 8.3 - Prob. 8.32PPCh. 8.4 - Prob. 8.33PPCh. 8.4 - Prob. 8.34PPCh. 8.4 - Calculate the final temperature, in degrees...Ch. 8.4 - Calculate the final temperature, in degrees...Ch. 8.4 - A gas sample has a pressure of 744 mmHg when the...Ch. 8.4 - Prob. 8.38PPCh. 8.4 - A tank contains isoflurane, an inhaled anesthetic,...Ch. 8.4 - Bacteria and viruses are inactivated by...Ch. 8.5 - Prob. 8.41PPCh. 8.5 - Prob. 8.42PPCh. 8.5 - Prob. 8.43PPCh. 8.5 - A sample of argon gas has a volume of 735 mL at a...Ch. 8.5 - A 124-mL bubble of hot gas initially at 212 °C and...Ch. 8.5 - A scuba diver 60 ft below the ocean surface...Ch. 8.6 - What happens to the volume of a bicycle tire or a...Ch. 8.6 - Prob. 8.48PPCh. 8.6 - Prob. 8.49PPCh. 8.6 - Prob. 8.50PPCh. 8.6 - Prob. 8.51PPCh. 8.6 - Prob. 8.52PPCh. 8.7 - A typical air sample in the lungs contains oxygen...Ch. 8.7 - Prob. 8.54PPCh. 8.7 - Prob. 8.55PPCh. 8.7 - In a gas mixture, the partial pressures are argon...Ch. 8.7 - A gas mixture containing oxygen, nitrogen, and...Ch. 8.7 - A gas mixture containing oxygen, nitrogen, and...Ch. 8.7 - Prob. 8.59PPCh. 8.7 - Prob. 8.60PPCh. 8.7 - Prob. 8.61PPCh. 8.7 - Prob. 8.62PPCh. 8 - Two flasks of equal volume and at the same...Ch. 8 - Prob. 8.64UTCCh. 8 - At 100 °C, which of the following diagrams (1, 2,...Ch. 8 - Indicate which diagram (1, 2, or 3) represents the...Ch. 8 - A balloon is filled with helium gas with a partial...Ch. 8 - Prob. 8.68UTCCh. 8 - Prob. 8.69UTCCh. 8 - Prob. 8.70UTCCh. 8 - Prob. 8.71APPCh. 8 - Prob. 8.72APPCh. 8 - Prob. 8.73APPCh. 8 - Prob. 8.74APPCh. 8 - A weather balloon has a volume of 750 L when...Ch. 8 - Prob. 8.76APPCh. 8 - A weather balloon is partially filled with Helium...Ch. 8 - Prob. 8.78APPCh. 8 - A gas mixture contains Oxygen and Argon at partial...Ch. 8 - Prob. 8.80APPCh. 8 - Prob. 8.81CPCh. 8 - You are doing research on planet X. The...Ch. 8 - Prob. 8.83CPCh. 8 - Prob. 8.84CP
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- When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.arrow_forwardQ6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of the two bases shown (on the -NH2). Include curved arrows to show the mechanism. O₂N- O₂N. -NH2 -NH2 a) Which of the two Bronsted bases above is the stronger base? Why? b) Identify the conjugate acids and conjugate bases for the reactants. c) Identify the Lewis acids and bases in the reactions.arrow_forwardQ5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OHarrow_forward
- potential energy Br b) Translate the Newman projection below to its wedge-and-dash drawing. F H. OH CH3 CI c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw a Newman projection of six conformations about the C2-C3 bond of isopentane. On the curve of potential energy versus angle of internal rotation for isopentane, label each energy maximum and minimum with one of the conformations. 0° 。 F A B D C angle of internal rotation E F 360° (=0°) JDownlarrow_forwardQ7: Identify the functional groups in these molecules a) CH 3 b) Aspirin: HO 'N' Capsaicin HO O CH3 CH 3arrow_forwardQ2: Name the following alkanesarrow_forward
- 1. Complete the following table in your laboratory notebook. Substance Formula Methanol CH3OH Ethanol C2H5OH 1-Propanol C3H7OH 1-Butanol C4H9OH Pentane C5H12 Hexane C6H14 Water H₂O Acetone C3H60 Structural Formula Molecular Weight (g/mol) Hydrogen Bond (Yes or No)arrow_forwardQ1: Compare the relative acidity in each pair of compounds. Briefly explain. (a) CH3OH vs NH 3 (b) HF vs CH3COOH (c) NH3 vs CH4 (d) HCI vs HI (e) CH3COOH vs CH3SH (f) H₂C=CH2 vs CH3 CH3 (g) compare the acidity of the two bolded hydrogens O. H N- (h) compare the acidity of the two bolded hydrogens, draw resonance structures to explain H H Harrow_forwardQ3: Rank the following molecules in order of decreasing boiling point: (a) 3-methylheptane; (b) octane; (c) 2,4-dimethylhexane; (d) 2,2,4-trimethylpentane.arrow_forward
- Q5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forwardThe ability of atoms to associate with each other depends ona) the electronic structure and its spatial orientation.b) the electron affinity.c) The other two answers are correct.arrow_forwardWhat is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why The initial volume of gas is 1.60 LL , the initial temperature of the gas is 23.0 °C°C , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches 48.2 °Carrow_forward
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