Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781337468039
Author: Skoog
Publisher: Cengage
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Chapter 8, Problem 8.6QAP
Interpretation Introduction

Interpretation:

The reason for lower intensity of atomic line for Li in a natural gas flame, 1800 oC in comparison to the hydrogen-oxygen flame, 2700 oC should be determined.

Concept introduction:

Spectral lines are lines which help in identifying the atoms and molecules. These are a result of absorption or emission of light in a comparatively narrower frequency range compared to the frequencies nearby.

With the increase in temperature, there are more atoms excited and more electron transition happens from ground state to excited state. This results in more intensity of the emission line.

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6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1
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