The functional group in compound one that reacts with BH 3 have to be identified and justified. Concept introduction: Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

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Answer 1

Question

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

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Answer 2

Question

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Expert Solution & Answer

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Answer 3

Question

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Expert Solution & Answer

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Answer 4

Question

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Expert Solution & Answer

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Answer 5

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Answer 6

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Answer 7

Chapter 8, Problem 85IP

(a)

Interpretation Introduction

Interpretation:

The functional group in compound one that reacts with BH3 have to be identified and justified.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The regiochemical and stereochemcial outcome of given reaction, and structure of compound 2 have to be predicted and drawn.

Concept introduction:

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.4 - Prob. 1CC Ch. 8.4 - Prob. 2CC Ch. 8.4 - Draw a mechanism for the following...Ch. 8.4 - Prob. 3PTS Ch. 8.4 - Prob. 4ATS Ch. 8.4 - Prob. 5CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 6PTS Ch. 8.5 - Prob. 8CC Ch. 8.5 - Prob. 9CC

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Chapter 8 Solutions