Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 8, Problem 8.5E
Interpretation Introduction

Interpretation:

The evidence for the statement “Hydrogen acts as both reducing and oxidizing agent” has to be described with chemical equations.

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It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]

Chapter 8 Solutions

Chemical Principles: The Quest for Insight

Ch. 8 - Prob. 8A.7ECh. 8 - Prob. 8A.8ECh. 8 - Prob. 8A.9ECh. 8 - Prob. 8A.10ECh. 8 - Prob. 8A.11ECh. 8 - Prob. 8A.12ECh. 8 - Prob. 8A.13ECh. 8 - Prob. 8A.14ECh. 8 - Prob. 8A.15ECh. 8 - Prob. 8A.16ECh. 8 - Prob. 8A.17ECh. 8 - Prob. 8A.18ECh. 8 - Prob. 8A.19ECh. 8 - Prob. 8A.20ECh. 8 - Prob. 8B.1ASTCh. 8 - Prob. 8B.1BSTCh. 8 - Prob. 8B.2ASTCh. 8 - Prob. 8B.2BSTCh. 8 - Prob. 8B.1ECh. 8 - Prob. 8B.2ECh. 8 - Prob. 8B.3ECh. 8 - Prob. 8B.4ECh. 8 - Prob. 8B.5ECh. 8 - Prob. 8B.6ECh. 8 - Prob. 8B.7ECh. 8 - Prob. 8B.8ECh. 8 - Prob. 8C.1ASTCh. 8 - Prob. 8C.1BSTCh. 8 - Prob. 8C.2BSTCh. 8 - Prob. 8C.1ECh. 8 - Prob. 8C.2ECh. 8 - Prob. 8C.3ECh. 8 - Prob. 8C.4ECh. 8 - Prob. 8C.5ECh. 8 - Prob. 8C.6ECh. 8 - Prob. 8D.1ASTCh. 8 - Prob. 8D.1BSTCh. 8 - Prob. 8D.2ASTCh. 8 - Prob. 8D.2BSTCh. 8 - Prob. 8D.1ECh. 8 - Prob. 8D.2ECh. 8 - Prob. 8D.3ECh. 8 - Prob. 8D.4ECh. 8 - Prob. 8D.5ECh. 8 - Prob. 8D.6ECh. 8 - Prob. 8D.7ECh. 8 - Prob. 8D.8ECh. 8 - Prob. 8E.1ASTCh. 8 - Prob. 8E.1BSTCh. 8 - Prob. 8E.2ASTCh. 8 - Prob. 8E.2BSTCh. 8 - Prob. 8E.1ECh. 8 - Prob. 8E.2ECh. 8 - Prob. 8E.3ECh. 8 - Prob. 8E.4ECh. 8 - Prob. 8E.5ECh. 8 - Prob. 8E.6ECh. 8 - Prob. 8E.7ECh. 8 - Prob. 8E.8ECh. 8 - Prob. 8F.1ASTCh. 8 - Prob. 8F.1BSTCh. 8 - Prob. 8F.2ASTCh. 8 - Prob. 8F.2BSTCh. 8 - Prob. 8F.1ECh. 8 - Prob. 8F.2ECh. 8 - Prob. 8F.3ECh. 8 - Prob. 8F.4ECh. 8 - Prob. 8F.5ECh. 8 - Prob. 8F.6ECh. 8 - Prob. 8G.1ASTCh. 8 - Prob. 8G.1BSTCh. 8 - Prob. 8G.2ASTCh. 8 - Prob. 8G.2BSTCh. 8 - Prob. 8G.1ECh. 8 - Prob. 8G.2ECh. 8 - Prob. 8G.3ECh. 8 - Prob. 8G.4ECh. 8 - Prob. 8G.5ECh. 8 - Prob. 8G.6ECh. 8 - Prob. 8G.7ECh. 8 - Prob. 8G.8ECh. 8 - Prob. 8G.9ECh. 8 - Prob. 8G.10ECh. 8 - Prob. 8H.1ASTCh. 8 - Prob. 8H.1BSTCh. 8 - Prob. 8H.2ASTCh. 8 - Prob. 8H.2BSTCh. 8 - Prob. 8H.1ECh. 8 - Prob. 8H.2ECh. 8 - Prob. 8H.3ECh. 8 - Prob. 8H.4ECh. 8 - Prob. 8H.5ECh. 8 - Prob. 8H.6ECh. 8 - Prob. 8H.7ECh. 8 - Prob. 8H.8ECh. 8 - Prob. 8H.10ECh. 8 - Prob. 8H.11ECh. 8 - Prob. 8H.12ECh. 8 - Prob. 8I.1ASTCh. 8 - Prob. 8I.1BSTCh. 8 - Prob. 8I.2ASTCh. 8 - Prob. 8I.2BSTCh. 8 - Prob. 8I.1ECh. 8 - Prob. 8I.2ECh. 8 - Prob. 8I.3ECh. 8 - Prob. 8I.5ECh. 8 - Prob. 8I.6ECh. 8 - Prob. 8I.7ECh. 8 - Prob. 8I.8ECh. 8 - Prob. 8I.9ECh. 8 - Prob. 8I.10ECh. 8 - Prob. 8I.11ECh. 8 - Prob. 8I.12ECh. 8 - Prob. 8I.13ECh. 8 - Prob. 8I.14ECh. 8 - Prob. 8I.15ECh. 8 - Prob. 8I.16ECh. 8 - Prob. 8J.1ASTCh. 8 - Prob. 8J.1BSTCh. 8 - Prob. 8J.1ECh. 8 - Prob. 8J.2ECh. 8 - Prob. 8J.3ECh. 8 - Prob. 8J.4ECh. 8 - Prob. 8J.5ECh. 8 - Prob. 8J.6ECh. 8 - Prob. 8J.7ECh. 8 - Prob. 8J.8ECh. 8 - Prob. 8.3ECh. 8 - Prob. 8.4ECh. 8 - Prob. 8.5ECh. 8 - Prob. 8.6ECh. 8 - Prob. 8.7ECh. 8 - Prob. 8.8ECh. 8 - Prob. 8.9ECh. 8 - Prob. 8.11ECh. 8 - Prob. 8.12ECh. 8 - Prob. 8.13ECh. 8 - Prob. 8.14ECh. 8 - Prob. 8.15ECh. 8 - Prob. 8.17ECh. 8 - Prob. 8.18ECh. 8 - Prob. 8.19ECh. 8 - Prob. 8.20ECh. 8 - Prob. 8.21ECh. 8 - Prob. 8.22ECh. 8 - Prob. 8.25ECh. 8 - Prob. 8.29ECh. 8 - Prob. 8.31CE
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