(a) Interpretation: The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry. Concept introduction: E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene . An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

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Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Answer 2

Question

Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

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Answer 3

Question

Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

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Answer 4

Question

Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

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Answer 5

Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Answer 6

Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Answer 7

Chapter 8, Problem 8.15P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, assuming it proceeds via E1 mechanism and paying attention to stereochemistry.

Concept introduction:

E1 reaction is a unimolecular elimination reaction, which takes place in two steps. In the first step, the bond between the carbon atom and the leaving group breaks to generate a carbocation, which is known as a heterolysis step. In the second step, a base removes a proton, forming an alkene. An E1 reaction produces a mixture of the E and Z configurations about a double bond formed in the products.

Answer 10

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Answer 12

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Answer 13

Ch. 8 - Prob. 8.1P Ch. 8 - Prob. 8.2P Ch. 8 - Prob. 8.3P Ch. 8 - Prob. 8.4P Ch. 8 - Prob. 8.5P Ch. 8 - Prob. 8.6P Ch. 8 - Prob. 8.7P Ch. 8 - Prob. 8.8P Ch. 8 - Prob. 8.9P Ch. 8 - Prob. 8.10P

Solution Summary: The author explains that the E1 reaction is a unimolecular elimination reaction, which takes place in two steps.

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