(a) Interpretation: Whether the species C 2 2 − is diamagnetic or paramagnetic needs to be determined. Concept introduction: The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

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Answer 1

Question

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

C. NaOMe, Br Br

Answer 2

Question

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

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Answer 3

Question

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

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Answer 4

Question

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

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Answer 5

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 6

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 7

Chapter 8, Problem 8.102SP

Interpretation Introduction

(a)

Interpretation:

Whether the species C22− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the species C22+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the species F2− is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the species Cl2 is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Whether the species Li2+ is diamagnetic or paramagnetic needs to be determined.

Concept introduction:

The magnetic properties of a substance are determined by examining electronic configuration of the species. Paramagnetic species are those in which unpaired electrons are remain in the orbital of any subshell and diamagnetic species does not contain unpaired electrons in the orbital of any subshell that means all electrons are paired.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 8 - Prob. 8.1P Ch. 8 - What is the number and geometric arrangement of...Ch. 8 - PRACTICE 8.3 Acetic acid, CH3CO2H , is the main...Ch. 8 - APPLY 8.4 Benzene, C6H6 , is a cyclic molecule in...Ch. 8 - PRACTICE 8.5 Identify the orbitals that overlap to...Ch. 8 - APPLY 8.6 Describe the bonding in propane, C3H8 ,...Ch. 8 - PRACTICE 8.7 Describe the hybridization of the...Ch. 8 - Describe the hybridization of each carbon atom in...Ch. 8 - Which orbitals overlap to form the sigma and pi...Ch. 8 - APPLY 8.10 Describe the hybridization of the...

Solution Summary: The author explains that the magnetic properties of a substance are determined by examining electronic configuration of the species.

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