Concept explainers
(a)
Interpretation:
If the 4-methylphenol will dissolve easily in aqueous NaOH solution than the pure water should be determined.
Concept Introduction:
The acid is a substance that gives
(b)
Interpretation:
If the 4-methylphenol will dissolve easily in aqueous NaHCO3 solution than the pure water should be determined.
Concept Introduction:
The acid is a substance that gives
(c)
Interpretation:
If the 4-methylphenol will dissolve easily in aqueous NH3 solution than the pure water should be determined.
Concept Introduction:
The acid is a substance that gives
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EP INTRO.TO GENERAL,ORGANIC...-OWL ACCE
- Predict which phase each of the following compounds would interact when dissolved in A) dichloromethane and aqueous HCI; and B) dichloromethane and aqueous NaOH. CH3 -N ОН N CH3 H3C `N' 'N' HO CH3 CH3 Acetylsalicylic acid (Aspirin) Acetaminophen Caffeinearrow_forwardCalculate the equilibrium constant for the acid–base reaction between the reactants in each of the following pairs: (a) HCl + H2O (b) CH3COOH + H2O (c) CH3NH2 + H2O (d) CH3N+H3 + H2Oarrow_forwardAmmonia can react as an acid or a base. a) What is the conjugate acid of ammonia? b) What is the conjugate base of ammonia? c) arist dit ons servbed as Complete the following acid-base reaction in which NH3(e) acts as both an acid and a base: OcH 6 HOONH3() + NH3() = OOH (d FOZH (s *АНИ (1 sqz ions to biosqu adtaviðarrow_forward
- NaHCO3 can deprotonate benzoic acid but cannot deprotonate phenol. On the other hand, NaOH can deprotonate both benzoic acid and phenol. Given this information, rank the molecules numbered I to V in order of decreasing acidity. COH cOH он H,0 H,CO, IV CH3 II I II (A) V > II >I > III > IV (В) II > 1 > V > III IV (C) II > V >I > IV > IIarrow_forwardIf a solid mixture of the three aromatic compounds shown below is placed in 3 M HCl, which is likely to dissolve?arrow_forwardConsider two acids: HCO2H (formic acid, pKa = 3.8) and pivalic acid [(CH3)3CCO,H, pK = 5.0]. (a) Which acid has the larger K? (b) Which acid is the stronger acid? (c) Which acid forms the stronger conjugate base? (d) When each acid is dissolved in water, for which acid does the equilibrium lie further to the right? %3D The pKa values in Table 2.1 span a large range (-7 to 50). The pK, scale is logarithmic. small difference in pK, translates into a large numerical difference, For example, the diffe between the pK, of NH3 (38) and CH2=CH, (44) is six pKa units. This means that NH, is one million times more acidic than CH,=CH,.arrow_forward
- Be sure to answer all parts. Which indicators that would be su ble for each of the following titrations: (a) CH;NH, with HBr thymol blue bromophenol blue methyl orange methyl red chlorophenol blue bromothymol blue O cresol red O phenolphthalein (b) HNO, with NaOH thymol blue bromophenol blue methyl orange methyl red chlorophenol blue bromothymol blue cresol red phenolphthalein (c) HNO, with KOH thymol blue O bromopbenol blue methyl orange methyl red chlorophenel bluearrow_forwardCalculate the pOH of a solution of methylamine and lye. Initially, [CH3NH2] = 1M and [NaOH] = 0.02M. CH3NH2(aq) + H2O(l) ↔ CH3NH3+(aq) + OH-(aq) Kb = 4.38x10-4 NaOH(aq) → Na+(aq) + OH-(aq) Strong base a. 1.70 b. 1.39 c. 1.68 d. 4.12 e. 2.33arrow_forwardIn the following reactions, indicate the acid, base, conjugate acid, and conjugate base. (a)HF + NH3→NH4++ F – (b)NaHSO4+ HClO3⇌H2SO4+ NaClO3arrow_forward
- Carbonic acid (H2CO3) and bicarbonate ion (HCO3-) are used as a buffer system to regulate the blood An exhausted marathon runner experienced acidosis as his blood pH become 7.15. What is the ratio of HCO3- to H2CO3 in this pH? (Ka of H2CO3 = 4.2 x 10-7)arrow_forwardConsider the acid-base nature of the salt NH4[C6H5COO], when it is dissolved in water. (1) What are the acid-base properties of the cation, NH4+? (2) What are the acid-base properties of the anion, C6H5COO™? (3) Would an aqueous solution of NH4[C6H5COO] be acidic, basic or neutral? C ◊arrow_forwardConsider the dissociation of hydrocyanic acid in aqueous solution HCN - CN + H* for which K, is 4.9 x 101°. (i) Find the pH of a solution initially 102 M in HCN, and the degree of dissociation of the HCN, a. (ii) To this solution is added more CN' until [CN'] = (0.1 M. What is the new pH of the solution? (ii) Without making a new numerical cakculation, explain qualitatively how the degree of dissociation would change if the solution is diluted.arrow_forward
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