Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 8, Problem 6E
How many
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
८८
2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 8 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 8 - Explain how and bonds are similar and how they...Ch. 8 - Draw a curve that describes the energy of a system...Ch. 8 - Explain why bonds occur at specific average bond...Ch. 8 - Use valence bond theory to explain the bonding in...Ch. 8 - Use valence bond theory to explain the bonding in...Ch. 8 - How many and bonds are present in the molecule...Ch. 8 - A friend tells you N2 has three bonds due to...Ch. 8 - Draw the Lewis structures for CO2 and CO, and...Ch. 8 - Why is the concept of hybridization required in...Ch. 8 - Give the shape that describes each hybrid orbital...
Ch. 8 - Explain why a carbon atom cannot form five bonds...Ch. 8 - What is the hybridization of the central atom in...Ch. 8 - A molecule with the formula AB3 could have one of...Ch. 8 - Methionine, CH3SCH2CH2CH(NH2)CO2H, is an amino...Ch. 8 - Sulfuric acid is manufactured by a series of...Ch. 8 - Two important industrial chemicals, ethene, C2H4,...Ch. 8 - For many years after they were discovered, it was...Ch. 8 - Consider nitrous acid, HNO2 (HONO). (a) Write a...Ch. 8 - Strike-anywhere matches contain a layer of KClO3...Ch. 8 - Identify the hybridization of each carbon atom in...Ch. 8 - Write Lewis structures for NF3 and PP5. On the...Ch. 8 - In addition to NF3, two other fluoro derivatives...Ch. 8 - The bond energy of a C—C single bond averages 347...Ch. 8 - For the carbonate ion, CO32, draw all of the...Ch. 8 - A useful solvent that will dissolve salts as well...Ch. 8 - For the molecule allene, H2C=C=CH2, give the...Ch. 8 - Identify the hybridization of the central atom in...Ch. 8 - Describe the molecular geometry and hybridization...Ch. 8 - For each of the following molecules, indicate the...Ch. 8 - For each of the following structures, determine...Ch. 8 - Draw the orbital diagram for carbon in CO2 showing...Ch. 8 - Sketch the distribution of electron density in the...Ch. 8 - How are the following similar, and how do they...Ch. 8 - If molecular orbitals are created by combining...Ch. 8 - Can a molecule with an odd number of electrons...Ch. 8 - Can a molecule with an even number of electrons...Ch. 8 - Why are bonding molecular orbitals lower in energy...Ch. 8 - Calculate the bond order for an ion with this...Ch. 8 - Explain why an electron in the bonding molecular...Ch. 8 - Predict the valence electron molecular orbital...Ch. 8 - Determine the bond order of each member of the...Ch. 8 - For the first ionization energy for an N2...Ch. 8 - Compare the atomic and molecular orbital diagrams...Ch. 8 - Which of the period 2 homonuclear diatomic...Ch. 8 - A friend tells you that the 2s orbital for...Ch. 8 - True or false: Boron contains 2s22p1 valence...Ch. 8 - What charge would be needed on F2 to generate an...Ch. 8 - Predict whether the MO diagram S2 would show s-p...Ch. 8 - Explain why N22+ is diamagnetic, while O24+, which...Ch. 8 - Using the MO diagrams, predict the bond order for...
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- in the scope of the SCH4U course! please show all steps as im still learning how to format my answers in the format given, thank you!arrow_forwardhelp me solve this HWarrow_forwardMolecules of the form AH2 can exist in two potential geometries: linear or bent. Construct molecular orbital diagrams for linear and bent CH2. Identify the relevant point group, include all of the appropriate symmetry labels and pictures, and fill in the electrons. Which geometry would you predict to be more stable, and why? (Please draw out the diagram and explain)arrow_forward
- Indicate the variation in conductivity with concentration in solutions of strong electrolytes and weak electrolytes.arrow_forwardThe molar conductivity of a very dilute solution of NaCl has been determined. If it is diluted to one-fourth of the initial concentration, qualitatively explain how the molar conductivity of the new solution will compare with the first.arrow_forwardWhat does the phrase mean, if instead of 1 Faraday of electricity, Q coulombs (Q/F Faradays) pass through?arrow_forward
- What characteristics should an interface that forms an electrode have?arrow_forwardFor a weak acid AcH, calculate the dissociated fraction (alpha), if its concentration is 1.540 mol L-1 and the concentration [H+] is 5.01x10-4 mol L-1.arrow_forwardIf the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.arrow_forward
- If the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.arrow_forwardIf the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.arrow_forwardDetermine the distance between the metal and the OHP layer using the Helm- holtz model when the electrode's differential capacitance is 145 μF cm². DATA: dielectric constant of the medium for the interfacial zone &r= lectric constant of the vacuum &0 = 8.85-10-12 F m-1 = 50, die-arrow_forward
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