Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
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a) (6pts) How many unique mono-chlorinated products can be formed and what are the
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6
Number of Unique
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b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Do the Lone Pairs get added bc its valence e's are a total of 6 for oxygen and that completes it or due to other reasons. How do we know the particular indication of such.
Chapter 8 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 8 - What is an aqueous solution? What is the...Ch. 8 - What is molarity? How is it useful?Ch. 8 - Explain how a strong electrolyte, a weak...Ch. 8 - What is an acid? Explain the difference between a...Ch. 8 - What does it mean for a compound to be soluble?...Ch. 8 - What are the solubility rules? How are they...Ch. 8 - Which cations and anions form compounds that are...Ch. 8 - What is a precipitation reaction? Give an example.Ch. 8 - How can you predict whether a precipitation...Ch. 8 - Explain how a molecular equation, a complete ionic...
Ch. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Prob. 13ECh. 8 - Explain the principles behind an acid-base...Ch. 8 - Prob. 15ECh. 8 - Which reactant types give rise to gas-evolution...Ch. 8 - Prob. 17ECh. 8 - What are oxidation states? How can oxidation...Ch. 8 - What happens to a substance when it becomes...Ch. 8 - In a redox reaction, which reactant is the...Ch. 8 - Prob. 21ECh. 8 - Prob. 22ECh. 8 - What is the molarity of NO3- in each solution?...Ch. 8 - What is the molarity of Cl- in each solution?...Ch. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - A laboratory procedure calls for making 400.0 mL...Ch. 8 - Prob. 28ECh. 8 - If 123 mL of a 1.1 M glucose solution is diluted...Ch. 8 - If 3.5 L of a 4.8 M SrCl2 solution is diluted to...Ch. 8 - To what volume should you dilute 50.0 mL of a 12 M...Ch. 8 - Prob. 32ECh. 8 - Consider the precipitation reaction:...Ch. 8 - Consider the reaction:...Ch. 8 - What is the minimum amount of 6.0 M H2SO4...Ch. 8 - What molarity of ZnCl2forms when 25.0 g of zinc...Ch. 8 - You mix a 25.0 mL sample of a 1.20 M potassium...Ch. 8 - Prob. 38ECh. 8 - For each compound (all water soluble), would you...Ch. 8 - Classify each compound as a strong electrolyte or...Ch. 8 - Determine whether each compound is soluble or...Ch. 8 - Prob. 42ECh. 8 - Prob. 43ECh. 8 - Complete and balance each equation. If no reaction...Ch. 8 - Write a molecular equation for the precipitation...Ch. 8 - Write a molecular equation for the precipitation...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - Mercury ions (Hg22+) can be removed from solution...Ch. 8 - Lead ions can be removed from solution by...Ch. 8 - Name each acid. Hl(aq) HNO3(aq) H2CO3(aq)Ch. 8 - Name each acid HCI(aq) HClO2(aq) H2SO4(aq)Ch. 8 - Provide the formula for each acid hydrofluoric...Ch. 8 - Provide the formula for each acid phosphoric acid...Ch. 8 - Write balanced molecular and net ionic equations...Ch. 8 - Write balanced molecular and net ionic equations...Ch. 8 - Complete and balance each acid-base equation...Ch. 8 - Complete and balance each acid-base equation...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - A 25.00-mL sample of an unknown HClO4solution...Ch. 8 - A 30.00-mL sample of an unknown H3PO4 solution is...Ch. 8 - Complete and balance each gas-evolution equation:...Ch. 8 - Prob. 64ECh. 8 - Write a balanced equation for the reaction between...Ch. 8 - Prob. 66ECh. 8 - Assign oxidation states to each atom in each...Ch. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Determine whether or not each reaction is a redox...Ch. 8 - Determine whether or not each reaction is a redox...Ch. 8 - Determine whether each redox reaction occurs...Ch. 8 - Determine whether each redox reaction occurs...Ch. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Which metal in the activity series reduce Al3+...Ch. 8 - Prob. 78ECh. 8 - Prob. 79ECh. 8 - Prob. 80ECh. 8 - People often use sodium bicarbonate as an antacid...Ch. 8 - Toilet bowl cleaners often contain hydrochloric...Ch. 8 - Prob. 83ECh. 8 - Prob. 84ECh. 8 - Predict the products and write a balanced...Ch. 8 - Predict the products and write a balanced...Ch. 8 - Prob. 87ECh. 8 - Prob. 88ECh. 8 - Prob. 89ECh. 8 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 8 - Find the volume of 0.110 M hydrochloric acid...Ch. 8 - Find the volume of 0.150 M sulfuric acid necessary...Ch. 8 - Treatment of gold metal with BrF3 and KF produces...Ch. 8 - We prepare a solution by mixing 0.10 L of 0.12 M...Ch. 8 - A solution contains Ag +and Hg2+ions. The addition...Ch. 8 - The water in lakes that have been acidified by...Ch. 8 - Recall from Section 8.5 that sodium carbonate is...Ch. 8 - A solution contains one or more of the following...Ch. 8 - A solution contains one or more of the following...Ch. 8 - Prob. 100ECh. 8 - Prob. 101ECh. 8 - Prob. 102ECh. 8 - Prob. 103ECh. 8 - Prob. 104ECh. 8 - Review the solubility rules. Without referring...Ch. 8 - Define and give an example of each of the...Ch. 8 - Prob. 107ECh. 8 - Prob. 108ECh. 8 - Prob. 1SAQCh. 8 - What mass (in grams) of Mg(NO3)2 is present in 145...Ch. 8 - Prob. 3SAQCh. 8 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 8 - Which solution forms a precipitate when mixed with...Ch. 8 - What is the net ionic equation for the reaction...Ch. 8 - What is the net ionic equation for the reaction...Ch. 8 - What is the net ionic equation for the reaction...Ch. 8 - What is the oxidation state of carbon in CO32-? +3...Ch. 8 - Prob. 10SAQCh. 8 - Prob. 11SAQCh. 8 - Which of these ions will spontaneously react with...
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- (5pts) Provide the complete arrow pushing mechanism for the chemical transformation depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O H I I CH3O-H H I ① Harrow_forward6. Draw the products) formed from the following reactions. (a) HIarrow_forwardDon't used Ai solutionarrow_forward
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