Chemistry for Changing Times
14th Edition
ISBN: 9780134212777
Author: John W. Hill; Terry W. McCreary
Publisher: Pearson Education (US)
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 8, Problem 62AP
When exposed to air containing hydrogen sulfide, lead-based paints turn black because the Pb2+ ions react with the H2S to form black lead sulfide (PbS). This has caused the darkening of old oil-based paintings. Hydrogen peroxide lightens the paints by oxidizing the black sulfide (S2-) to white sulfates (SO42-).
(a) Write the equation for the darkening reaction.
(b)Write the equation for this reaction that lightens the paints.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Chapter 8 Solutions
Chemistry for Changing Times
Ch. 8 - Prob. 1RQCh. 8 - Prob. 2RQCh. 8 - Prob. 3RQCh. 8 - Prob. 4RQCh. 8 - Prob. 5RQCh. 8 - Prob. 6RQCh. 8 - Prob. 7RQCh. 8 - Prob. 8RQCh. 8 - Prob. 9RQCh. 8 - Prob. 10RQ
Ch. 8 - Prob. 11RQCh. 8 - Prob. 12RQCh. 8 - Prob. 13RQCh. 8 - Prob. 14RQCh. 8 - Prob. 15RQCh. 8 - Prob. 16PCh. 8 - Prob. 17PCh. 8 - Prob. 18PCh. 8 - Prob. 19PCh. 8 - 20. Write a balanced reduction half-reaction...Ch. 8 - Prob. 21PCh. 8 - Prob. 22PCh. 8 - Prob. 23PCh. 8 - Prob. 24PCh. 8 - Prob. 25PCh. 8 - Prob. 26PCh. 8 - Prob. 27PCh. 8 - Prob. 28PCh. 8 - Prob. 29PCh. 8 - Prob. 30PCh. 8 - Prob. 31PCh. 8 - Prob. 32PCh. 8 - Prob. 33PCh. 8 - Prob. 34PCh. 8 - Prob. 35PCh. 8 - Prob. 36PCh. 8 - Prob. 37PCh. 8 - Prob. 38PCh. 8 - Prob. 39PCh. 8 - Prob. 40PCh. 8 - Prob. 41PCh. 8 - Prob. 42PCh. 8 - Prob. 43PCh. 8 - 44. Tantalum, a metal used m electronic devices...Ch. 8 - Prob. 45PCh. 8 - Prob. 46PCh. 8 - Prob. 47PCh. 8 - Prob. 48PCh. 8 - Prob. 49PCh. 8 - Prob. 50PCh. 8 - Prob. 51PCh. 8 - Prob. 52PCh. 8 - Prob. 53PCh. 8 - Prob. 54PCh. 8 - Prob. 55APCh. 8 - Prob. 56APCh. 8 - Prob. 57APCh. 8 - Prob. 58APCh. 8 - Prob. 59APCh. 8 - Prob. 60APCh. 8 - Prob. 61APCh. 8 - When exposed to air containing hydrogen sulfide,...Ch. 8 - Prob. 63APCh. 8 - Prob. 64APCh. 8 - Prob. 65APCh. 8 - Prob. 66APCh. 8 - Prob. 67APCh. 8 - Prob. 68APCh. 8 - Prob. 69APCh. 8 - Prob. 70APCh. 8 - Prob. 71APCh. 8 - Prob. 72APCh. 8 - Prob. 73APCh. 8 - Prob. 74APCh. 8 - Prob. 75APCh. 8 - Prob. 76APCh. 8 - Prob. 77APCh. 8 - Prob. 78APCh. 8 - Prob. 79APCh. 8 - Prob. 80APCh. 8 - Prob. 8.1CTECh. 8 - Prob. 8.2CTECh. 8 - Prob. 8.3CTECh. 8 - Prob. 8.4CTECh. 8 - Prob. 8.5CTECh. 8 - Prob. 8.6CTECh. 8 - Prob. 8.7CTECh. 8 - Prob. 1CGPCh. 8 - Prob. 2CGPCh. 8 - Prob. 3CGPCh. 8 - Prob. 4CGPCh. 8 - Prob. 5CGPCh. 8 - Prob. 1CHQCh. 8 - Prob. 2CHQCh. 8 - Prob. 3CHQCh. 8 - Prob. 4CHQCh. 8 - Prob. 5CHQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Calcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forwardAn electrode is prepared from liquid mercury in contact with a saturated solution of mercury(I) chloride, Hg2Cl, containing 1.00 M Cl . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.268 V. What is the solubility product of mercury(I) chloride?arrow_forwardWrite balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.arrow_forward
- Chlorine, Cl2, is produced commercially by the electrolysis of aqueous sodium chloride. The anode reaction is 2Cl(aq)Cl2(g)+2e How long will it take to produce 2.00 kg of chlorine if the current is 5.00 102 A?arrow_forwardThe space shuttle Orbiter utilizes the oxidation of methylhydrazine by dinitrogen tetroxide for propulsion: 4N2H3CH3(l)+5N2O4(l)12H2O(g)+9N2(g)+4CO2(g) Calculate H for this reactionarrow_forward. What is the oxidation state of chlorine in each of the following substances? a. CIF c. HCI b. Cl2 d. HClOarrow_forward
- Three reactions very important to the semiconductor industry are The reduction of silicon dioxide to crude silicon, SiO2(s) + 2 C(s) → Si(s) + 2 CO(g) ΔrH° = 689.9 kJ/mol The formation of silicon tetrachloride from crude silicon, Si(s) + 2 Cl2(g) → SiCl4(g) ΔrH° = −657.01 kJ/mol The reduction of silicon tetrachloride to pure silicon with magnesium, SiCl4(g) + 2 Mg(s) → 2 MgCl2(s) + Si(s) ΔrH° = −625.6 kJ/mol Calculate the overall enthalpy change when 1.00 mol sand, SiO2, changes into very pure silicon by this series of reactions.arrow_forwardA 1.0-L sample of 1.0 M HCl solution has a 10.0 A current applied for 45 minutes. What is the pH of the solution after the electricity has been turned off?arrow_forwardSome metals, such as thallium, can be oxidized to more than one oxidation state. Obtain the balanced net ionic equations for the following oxidation reduction reactions, in which nitric acid is reduced to nitric oxide, NO. a Oxidation of thallium metal to thallium(I) ion by nitric acid. b Oxidation of thallium(I) ion to thallium(III) ion by nitric acid. c Oxidation of thallium metal to thallium(III) by nitric acid. [Consider adding the a and b equations.]arrow_forward
- Phosphorous acid, H3PO3, is oxidized to phosphoric acid, H3PO4, by nitric acid, which is reduced to nitrogen monoxide, NO. Write the balanced equation for this reaction.arrow_forwardDescribe the electrolytic process for refining copper.arrow_forwardThe development of lightweight batteries is an ongoing research effort combining many of the physical sciences. You are a member of an engineering team trying to develop a lightweight battery that will effectively react with O2(g) from the atmosphere as an oxidizing agent. A reducing agent must be chosen for this battery that will be lightweight, have nontoxic products, and react spontaneously with oxygen. Using data from Appendix I, suggest a likely reducing agent, being sure these conditions are met. Are there any drawbacks to your selection?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Balancing Redox Reactions in Acidic and Basic Conditions; Author: Professor Dave Explains;https://www.youtube.com/watch?v=N6ivvu6xlog;License: Standard YouTube License, CC-BY