Introducing Chemistry
6th Edition
ISBN: 9780134557373
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 8, Problem 5E
what is the general from of the solution map for problems in which you are given the mass of a. reactant in a
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 8 Solutions
Introducing Chemistry
Ch. 8 - Q1. Sulfur and fluorine react to form sulfur...Ch. 8 - Hydrogen chloride gas and oxygen gas react to form...Ch. 8 - Sodium reacts with fluorine to form sodium...Ch. 8 - Consider the hypothetical reaction shown here. If...Ch. 8 - Prob. 5SAQCh. 8 - Prob. 6SAQCh. 8 - Sodium and chlorine react to form sodium chloride....Ch. 8 - A reaction has a theoretical yield of 22.8 g. when...Ch. 8 - Titanium can be obtained from its oxide by the...Ch. 8 - Which statement best describes an exothermic...
Ch. 8 - Consider the generic reaction: A+2BAB2Hrxn=155kJ...Ch. 8 - Q12. Hydrogen gas reacts with oxygen to form...Ch. 8 - Prob. 1ECh. 8 - Nitrogen and hydrogen can react to from ammonia:...Ch. 8 - 3. Write the conversion factor that you would use...Ch. 8 - 4. What is wrong with this statement in reference...Ch. 8 - 5 what is the general from of the solution map...Ch. 8 - 6. Consider the recipe for making tomato and...Ch. 8 - 7 In a chemical reaction, what is the limiting...Ch. 8 - Prob. 8ECh. 8 - In a chemical reaction, what are the actual yield...Ch. 8 - If you are given a chemical equation and specific...Ch. 8 - 11. Consider the generic chemical...Ch. 8 - Prob. 12ECh. 8 - What is the enthalpy of reaction (Hrxn)? Why is...Ch. 8 - Explain the relationship between the sign of Hrxn...Ch. 8 - Consider the generic chemical reaction: A+2BC How...Ch. 8 - Consider the generic chemical reaction: 2A+3B3C...Ch. 8 - 17. For the reaction shown, calculate how many...Ch. 8 - 18. For the reaction shown, calculate how many...Ch. 8 - 19. Dihydrogen monosulfide reacts with sulfur...Ch. 8 - 20. Chlorine gas reacts with fluorine gas...Ch. 8 - For each reaction, calculate how many moles of...Ch. 8 - 22. For each reaction, calculate how many moles of...Ch. 8 - 23. For the reaction shown, calculate how many...Ch. 8 - 24. For the reaction shown, calculate how many...Ch. 8 - Consider the balanced equation:...Ch. 8 - 26. Consider the balance equation:
Complete the...Ch. 8 - 27. Consider the unbalanced equation for the...Ch. 8 - 28. Consider the unbalanced equation for the...Ch. 8 - 29. Consider the unbalanced equation for the...Ch. 8 - 30. Consider the unbalanced equation for the...Ch. 8 - Prob. 31ECh. 8 - 32. For the reaction shown, calculate how many...Ch. 8 - For each of the reactions, calculate how many...Ch. 8 - 34. For each of the reactions, calculate how many...Ch. 8 - 35. For the reaction shown, calculate how many...Ch. 8 - 36. For the reaction shown, calculate how many...Ch. 8 - Prob. 37ECh. 8 - Consider the balanced equation for the combustion...Ch. 8 - 39. For each acid–base reaction, calculate how...Ch. 8 - 40. For each precipitation reaction, calculate how...Ch. 8 - Sulfuric acid can dissolve aluminum metal...Ch. 8 - Hydrochloric acid can dissolve solid iron...Ch. 8 - 43. Consider the generic chemical equation:
a....Ch. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - 49. For the reaction shown, calculate the...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - Consider the generic reaction between reactants A...Ch. 8 - Consider the reaction between reactants S and O2:...Ch. 8 - Consider the reaction 4HCI(g)+O2(g)2H2O(g)+2Cl2(g)...Ch. 8 - 54. Consider the reaction
Each molecular diagram...Ch. 8 - 55. For the reaction shown, find the limiting...Ch. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - 58. If the theoretical yield of a reaction is 24.8...Ch. 8 - If the theoretical yield of reaction is 0.118 g...Ch. 8 - 61. Consider the reaction between calcium oxide...Ch. 8 - Consider the reaction between sulfur trioxide and...Ch. 8 - Consider the reaction between NiS2 and O2:...Ch. 8 - Consider the reaction between HCI and O2...Ch. 8 - Lead ions can be precipitate form solution with...Ch. 8 -
Ch. 8 - Consider the reaction between TiO2 and C:...Ch. 8 - 68. Consider the raction between N2H4 and N2O4:
A...Ch. 8 - 69. Classify each process as exothermic or...Ch. 8 - 70. Classify each process as exothermic or...Ch. 8 - Consider the generic reaction: A+2BCHrxn=55kJ...Ch. 8 - Prob. 72ECh. 8 - Consider the equation for the combustion of...Ch. 8 - The equation for the combustion of CH4 (the main...Ch. 8 - 75. Octane (C8H18) is a component of gasoline that...Ch. 8 - 76. The evaporation of water is...Ch. 8 - Consider the reaction:...Ch. 8 - Prob. 78ECh. 8 - A solution contains an unknown mass of dissolved...Ch. 8 - 80. A solution contains an unknown mass of...Ch. 8 - 81. Sodium bicarbonate is often used as an antacid...Ch. 8 - Toilet bowl cleaners often contain hydrochloric...Ch. 8 - 83. The combustion of gasoline produces carbon...Ch. 8 - Many home barbecues are fueled with propane gas...Ch. 8 - Prob. 85ECh. 8 - 86. Magnesium ions can be precipitated from...Ch. 8 - Hydrogen gas can be prepared in the laboratory by...Ch. 8 - Sodium peroxide (Na2O2) reacts with water to form...Ch. 8 - Prob. 89ECh. 8 - Pure oxygen gas can be prepared in the laboratory...Ch. 8 - 91. Aspirin can be made in the laboratory by...Ch. 8 - 92. The combustion of liquid ethanol produces...Ch. 8 - Urea (CH4N2 O), a common fertilizer, can be...Ch. 8 - 94. Silicon, which occurs in nature as SiO2, is...Ch. 8 - 95. The ingestion of lead from food, water, or...Ch. 8 - Prob. 96ECh. 8 - The propane fuel (C3H8) used in gas barbecues...Ch. 8 - Charcoal is primarily carbon. Determine the mass...Ch. 8 - 99. A loud classroom demonstration involves...Ch. 8 - 100. A hydrochloric acid solution will neutralize...Ch. 8 - 101. Scientists have grown progressively more...Ch. 8 - Prob. 102ECh. 8 - What volume of air is needed to burn an entire...Ch. 8 - Have each member of your group choose a...Ch. 8 - 105. Consider the combustion of propane:
a....
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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