The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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Answer 1

Question

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Answer 2

Question

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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Answer 3

Question

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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Answer 4

Question

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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Answer 5

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 6

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 7

Chapter 8, Problem 59E

(a)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 8

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 9

(b)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 10

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 11

(c)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 12

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 13

(d)

Interpretation Introduction

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8 - Prob. 1SAQ Ch. 8 - Q2. Which electron in sulfur is most shielded from...Ch. 8 - Prob. 3SAQ Ch. 8 - Prob. 4SAQ Ch. 8 - Prob. 5SAQ Ch. 8 - Prob. 6SAQ Ch. 8 - Prob. 7SAQ Ch. 8 - Prob. 8SAQ Ch. 8 - Prob. 9SAQ Ch. 8 - Prob. 10SAQ

The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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To determine: The effective nuclear charge experienced by the valence electrons of K atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

To determine: The effective nuclear charge experienced by the valence electrons of Ca atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

To determine: The effective nuclear charge experienced by the valence electrons of O atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

To determine: The effective nuclear charge experienced by the valence electrons of C atom if core electrons completely shielded valence electrons from nuclear charge and if valence electrons did not shield one another from nuclear charge at all.

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