(a) Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn. Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Question

16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

Answer 1

Question

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN

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Answer 2

Question

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

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Answer 3

Question

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

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Answer 4

Question

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

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Answer 5

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 6

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Answer 7

Chapter 8, Problem 56P

Interpretation Introduction

(a)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide used, the base being used and the leaving group present.

Answer 8

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 9

Interpretation Introduction

(b)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 10

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 11

Interpretation Introduction

(c)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 12

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 13

Interpretation Introduction

(d)

Interpretation: The reason as to why the given reaction does not afford the major product that is given is to be explained and the structure of the major product actually formed is to be drawn.

Concept introduction: In elimination and substitution reactions, the product formed depends on the type of halide in question, the base being used and the leaving group present.

Answer 14

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Answer 25

Ch. 8.1 - Problem 8.1 Label the and carbons in each alkyl...Ch. 8.2 - Problem 8.2 Classify each alkene in the following...Ch. 8.2 - Prob. 3P Ch. 8.2 - Prob. 4P Ch. 8.2 - Problem 8.5 Label each pair of alkenes as...Ch. 8.2 - Problem 8.6 Which alkene in each pair is more...Ch. 8.2 - Problem 8.7 Several factors can affect alkene...Ch. 8.4 - Prob. 8P Ch. 8.4 - Prob. 9P Ch. 8.4 - Prob. 10P

Solution Summary: The author explains that the alkyl halide is primary and base is a strong, sterically hindered base which prefers only elimination reaction.

Chapter 8 Solutions