Interpretation:
The outcome of the reaction of tert-pentylchloride with propene and its mechanistic steps are to be predicted.
Concept introduction:
Electrophiles are electron-deficient species, which has positive or partially positive charge. Lewis acids are electrophiles, which accept electron pair.
Nucleophiles are electron-rich species, which has negative or partially negative charge. Lewis bases are nucleophiles, which donate electron pair.
Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a
Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules.
Carbocation is a molecule having a carbon atom bearing three bonds and a positive formal charge.
Carbocation are generally unstable because they do not have eight electrons to satisfy the octet rule.
The order of stability of carbocation is such that the tertiary carbocation is the most stable whereas the primary carbocation is the least stable, and secondary carbocation lies between primary and tertiary carbocations.
If primary carbocation is obtained in product, it rearranges itself to secondary or tertiary carbocation to form more stable product.
If secondary carbocation is obtained in product, it rearranges itself to tertiary carbocation to form more stable product.

Want to see the full answer?
Check out a sample textbook solution
Chapter 8 Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
- What is the product of the following reaction? Please explain what is happening in this question. Provide a detailed explanation and a drawing showing how the reagent is reacting with the catalysts to product the correct product. The correct answer is B.arrow_forwardWhat is the missing intermediate 1 and the final product 2. Please include a detailed explanation explaining the steps of malonic ester synthesis. Please include drawings of the intermediate and how it occurs and how the final product is former.arrow_forwardWhat would be the reagents and conditions above and below the arrow that will complete the proposed acetoacetic ester synthesis? If it cannot be done efficiently, then I will choose that answer. There could be 2 or 4 reagents involved. Please provide a detailed explanation and drawings showing how it would proceed with the correct reagents.arrow_forward
- For benzene, the ∆H° of vaporization is 30.72 kJ/mol and the ∆S° of vaporization is 86.97 J/mol・K. At 1.00 atm and 228.0 K, what is the ∆G° of vaporization for benzene, in kJ/mol?arrow_forwardThe reaction Q(g) + R(g) → Z(l) is shown to be exothermic. Which of the following is true concerning the reaction. it is spontaneous only at High T, it is spontaneous at low T it is nonspontaneous at all T it is spontanrous at all T. it is non spontaneous only at low T.arrow_forwardThe reaction Q(g) + R(g) → Z(l) is shown to be exothermic. Which of the following is true concerning the reactionarrow_forward
- Which of the following has the largest standard molar entropy, S° (298.15 K) He H2 NaCl KBr Hgarrow_forwardWhich of the following is true for a particular reaction if ∆G° is -40.0 kJ/mol at 290 K and –20.0 kJ/mol at 390 K?arrow_forwardWhat is the major product of the following reaction? O O OH OH 1. BH 2. H₂O₂, NaOH OH OHarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

