Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
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Question
Chapter 8, Problem 55PP
Interpretation Introduction
Interpretation:
Mechanism should be drawn for the given reaction.
Concept introduction:
- Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.
- Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.
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I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq)
Experiment
[I-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
Calculate the overall order of this reaction using the table data.
0.0025
0.000069
0.0025
0.000140
H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)·
•••
Experiment [H2 O2]o (M)
[I]o (M) [H+]。 (M)
Initial rate (M/s)
1
0.15
0.15
0.05
0.00012
234
0.15
0.3
0.05
0.00024
0.3
0.15
0.05
0.00024
0.15
0.15
0.1
0.00048
Calculate the overall order of this reaction using the table data.
The U. S. Environmental Protection Agency (EPA) sets
limits on healthful levels of air pollutants. The
maximum level that the EPA considers safe for lead air
pollution is 1.5 μg/m³
Part A
If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung
volume of 5.40 L.)
ΜΕ ΑΣΦ
= 2.35 1013
?
atoms
! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step.
No credit lost. Try again.
Chapter 8 Solutions
Organic Chemistry
Ch. 8.4 - Prob. 1CCCh. 8.4 - Prob. 2CCCh. 8.4 - Draw a mechanism for the following...Ch. 8.4 - Prob. 3PTSCh. 8.4 - Prob. 4ATSCh. 8.4 - Prob. 5CCCh. 8.4 - Prob. 2LTSCh. 8.4 - Prob. 6PTSCh. 8.5 - Prob. 8CCCh. 8.5 - Prob. 9CC
Ch. 8.5 - Prob. 3LTSCh. 8.5 - Prob. 10PTSCh. 8.5 - Prob. 11ATSCh. 8.6 - Prob. 12CCCh. 8.6 - Prob. 13CCCh. 8.7 - Below are several examples of...Ch. 8.7 - Prob. 15CCCh. 8.7 - Prob. 4LTSCh. 8.7 - Prob. 16PTSCh. 8.7 - Prob. 17ATSCh. 8.8 - Prob. 5LTSCh. 8.8 - Prob. 18PTSCh. 8.8 - Prob. 19ATSCh. 8.9 - Prob. 20CCCh. 8.9 - Predict the major product(s) for the following...Ch. 8.9 - Prob. 21PTSCh. 8.9 - Prob. 22ATSCh. 8.9 - Prob. 23ATSCh. 8.10 - Prob. 7LTSCh. 8.10 - Prob. 24PTSCh. 8.10 - Prob. 25ATSCh. 8.10 - Prob. 26ATSCh. 8.11 - Prob. 27CCCh. 8.12 - Prob. 8LTSCh. 8.12 - Prob. 28PTSCh. 8.12 - Prob. 29PTSCh. 8.12 - Prob. 30ATSCh. 8.13 - Prob. 9LTSCh. 8.13 - Prob. 31PTSCh. 8.13 - Prob. 32ATSCh. 8.13 - Prob. 33ATSCh. 8.13 - Prob. 34ATSCh. 8.14 - Prob. 10LTSCh. 8.14 - Prob. 35PTSCh. 8.14 - Prob. 36ATSCh. 8.14 - Prob. 11LTSCh. 8.14 - Prob. 37PTSCh. 8.14 - Bioethanol, ethanol produced by fermentation of...Ch. 8.14 - Prob. 12LTSCh. 8.14 - Prob. 39PTSCh. 8.14 - Prob. 40ATSCh. 8 - Prob. 41PPCh. 8 - Prob. 42PPCh. 8 - Prob. 43PPCh. 8 - Prob. 44PPCh. 8 - Prob. 45PPCh. 8 - Prob. 46PPCh. 8 - Prob. 47PPCh. 8 - Prob. 48PPCh. 8 - Prob. 49PPCh. 8 - Prob. 50PPCh. 8 - Prob. 51PPCh. 8 - Prob. 52PPCh. 8 - Prob. 53PPCh. 8 - Prob. 54PPCh. 8 - Prob. 55PPCh. 8 - Prob. 56PPCh. 8 - Prob. 57PPCh. 8 - Prob. 58PPCh. 8 - Prob. 59PPCh. 8 - Prob. 60PPCh. 8 - Prob. 61PPCh. 8 - Prob. 62PPCh. 8 - Prob. 63PPCh. 8 - Prob. 64PPCh. 8 - Prob. 65PPCh. 8 - Prob. 66PPCh. 8 - Prob. 67PPCh. 8 - Prob. 68PPCh. 8 - Prob. 69PPCh. 8 - Prob. 70PPCh. 8 - Prob. 71PPCh. 8 - Prob. 72PPCh. 8 - Prob. 73PPCh. 8 - Prob. 74IPCh. 8 - Prob. 75IPCh. 8 - Prob. 76IPCh. 8 - Prob. 77IPCh. 8 - Prob. 78IPCh. 8 - Prob. 79IPCh. 8 - Prob. 80IPCh. 8 - Prob. 81IPCh. 8 - Prob. 82IPCh. 8 - Prob. 83IPCh. 8 - Prob. 84IPCh. 8 - Prob. 85IPCh. 8 - Prob. 86IPCh. 8 - Prob. 87IPCh. 8 - Prob. 88IPCh. 8 - Prob. 90IPCh. 8 - Prob. 91IPCh. 8 - Prob. 92IPCh. 8 - Prob. 93CPCh. 8 - Prob. 95CPCh. 8 - Prob. 96CP
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