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OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
8th Edition
ISBN: 9781305863170
Author: William L. Masterton; Cecile N. Hurley
Publisher: Cengage Learning US
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Textbook Question
Chapter 8, Problem 54QAP
How many L
atm are equal to 12.2 kJ of work?
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 8 Solutions
OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
Ch. 8 - Principles of Heat Flow Titanium is a metal used...Ch. 8 - Prob. 2QAPCh. 8 - Copper is used in building the integrated...Ch. 8 - Mercury was once used in thermometers and...Ch. 8 - The specific heat of aluminum is 0.902J/gC. How...Ch. 8 - Chromium has a specific heat of 0.450J/gC. How...Ch. 8 - Magnesium sulfate is often used in first-aid hot...Ch. 8 - Sodium chloride is added in cooking to enhance the...Ch. 8 - When 375 mL of water (d=1.00g/mL) at 32C are mixed...Ch. 8 - How many mL of water at 10C (2 significant...
Ch. 8 - When one mol of KOH is neutralized by sulfuric...Ch. 8 - The heat of neutralization, Hneut, can be defined...Ch. 8 - Fructose is a sugar commonly found in fruit. A...Ch. 8 - In earlier times, ethyl ether was commonly used as...Ch. 8 - Isooctane is a primary component of gasoline and...Ch. 8 - Ethyl alcohol, C2H5OH, is the intoxicating agent...Ch. 8 - Acetic acid, HC2H3O2, is responsible for the sour...Ch. 8 - Acetylene, C2H2, is used in welding torches. It...Ch. 8 - Salicylic acid, C7H6O3, is one of the starting...Ch. 8 - Methanol (CH3OH) is also known as wood alcohol and...Ch. 8 - Nitrogen oxide (NO) has been found to be a key...Ch. 8 - Small amounts of oxygen gas can be prepared in the...Ch. 8 - In the late eighteenth century Priestley prepared...Ch. 8 - Prob. 24QAPCh. 8 - Strontium metal is responsible for the red color...Ch. 8 - Nitroglycerin, C3H5(NO3)3(l), is an explosive most...Ch. 8 - A typical fat in the body is glyceryl trioleate,...Ch. 8 - Use the same fat described in Question 27. (a)...Ch. 8 - Which requires the absorption of a greater amount...Ch. 8 - Which evolves more heat—freezing 100.0 g of...Ch. 8 - A student is asked to calculate the amount of heat...Ch. 8 - Follow the step-wise process outlined in Problem...Ch. 8 - A lead ore, galena, consisting mainly of lead(II)...Ch. 8 - A reaction used to produce the silicon for...Ch. 8 - Given the following thermochemical equations,...Ch. 8 - Given the following thermochemical equations:...Ch. 8 - Write thermochemical equations for the...Ch. 8 - Write thermochemical equations for the formation...Ch. 8 - Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is...Ch. 8 - Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What...Ch. 8 - Limestone, CaCO3, when subjected to a temperature...Ch. 8 - When hydrazine reacts with oxygen, nitrogen gas...Ch. 8 - Use Table 8.3 to obtain AHO for the following...Ch. 8 - Use Table 8.3 to obtain H for the following...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - When one mole of nitroglycerine, C3H5(NO3)3(l)...Ch. 8 - When one mole of calcium carbonate reacts with...Ch. 8 - Chlorine trifluoride is a toxic, intensely...Ch. 8 - When one mole of ethylene gas, C2H4, reacts with...Ch. 8 - Glucose, C6H12O6(s), (H f =1275.2kJ/mol) is...Ch. 8 - When ammonia reacts with dinitrogen oxide gas (H f...Ch. 8 - How many kJ are equal to 3.27 L atm of work?Ch. 8 - How many L atm are equal to 12.2 kJ of work?Ch. 8 - Find (a) E when a gas absorbs 18 J of heat and has...Ch. 8 - Calculate (a) q when a system does 54 J of work...Ch. 8 - Consider the following reaction in a vessel with a...Ch. 8 - Consider the following reaction in the vessel...Ch. 8 - Determine the difference between H and E at 25C...Ch. 8 - For the vaporization of one mole of bromine at...Ch. 8 - Consider the combustion of propane, C3H8, the fuel...Ch. 8 - Consider the combustion of one mole of methyl...Ch. 8 - Butane gas, C4H10, is sold to campers as bottled...Ch. 8 - The BTU (British thermal unit) is the unit of...Ch. 8 - Natural gas companies in the United States use the...Ch. 8 - Prob. 66QAPCh. 8 - Given the following reactions,...Ch. 8 - In World War II, the Germans made use of otherwise...Ch. 8 - Prob. 69QAPCh. 8 - Consider the reaction between methane and oxygen...Ch. 8 - Consider burning ethane gas, C2H6 in oxygen...Ch. 8 - On complete combustion at constant pressure, a...Ch. 8 - Microwave ovens convert radiation to energy. A...Ch. 8 - In 2010, 3.30109 gallons of gasoline were consumed...Ch. 8 - Some solar-heated homes use large beds of rocks to...Ch. 8 - Consider a solution prepared by dissolving 10.00 g...Ch. 8 - Draw a cylinder with a movable piston containing...Ch. 8 - Redraw the cylinder in Question 77 after work has...Ch. 8 - Which statement(s) is/are true about bond...Ch. 8 - Equal masses of liquid A, initially at 100C, and...Ch. 8 - Determine whether the statements given below are...Ch. 8 - An exothermic reaction is carried out in a...Ch. 8 - Determine whether the statements given below are...Ch. 8 - Microwave ovens emit microwave radiation that is...Ch. 8 - On a hot day, you take a six-pack ot a on a pcmc,...Ch. 8 - Prob. 86QAPCh. 8 - The thermite reaction was once used to weld rails:...Ch. 8 - A sample of sucrose, C12H22O11, is contaminated by...Ch. 8 - A wad of steel wool (specific heat=0.45J/gC) at...Ch. 8 - Consider a metal ion A2+ and its nitrate salt, In...
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- For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.arrow_forwardA molecule shows peaks at 1379, 1327, 1249, 739 cm-1. Draw a diagram of the energy levels for such a molecule. Draw arrows for the possible transitions that could occur for the molecule. In the diagram imagine exciting an electron, what are its various options for getting back to the ground state? What process would promote radiation less decay? What do you expect for the lifetime of an electron in the T1 state? Why is phosphorescence emission weak in most substances? What could you do to a sample to enhance the likelihood that phosphorescence would occur over radiationless decay?arrow_forwardRank the indicated C—C bonds in increasing order of bond length. Explain as why to the difference.arrow_forward
- The SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal charges. Cl: Add/Remove step G Click and drag to start drawing a structure.arrow_forwardPlease correct answer and don't use hand ratingarrow_forwardA monochromatic light with a wavelength of 2.5x10-7m strikes a grating containing 10,000 slits/cm. Determine the angular positions of the second-order bright line.arrow_forward
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