Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781305176461
Author: Kotz
Publisher: Cengage
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Chapter 8, Problem 41PS

Which of the following molecules is(are) polar? For each polar molecule indicate the direction of polarity—that is, which is the negative end, and which is the positive end of the molecule.

  1. (a) BeCl2
  2. (b) HBF2
  3. (c) CH3Cl
  4. (d) SO3

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: Check whether the given molecule is polar or not. If the molecule is polar then the direction of polarity has to be indicated.

Concept Introduction:

Polar molecules are the molecules having a positive and negative end and so there will be a charge separation.

A polar molecule is a molecule where the polar bonds are asymmetrically arranged (the dipoles do not cancel)

A nonpolar molecule is a molecule with no polar bonds or a molecule where the polar bonds are symmetrically arranged.

In polar molecule the charge separation occurred with respect to the difference in electronegativity of atoms in the molecule.

Direction of dipole moment in a molecule is can be represented as follows,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  1

Different types of molecules and their geometry in accordance with the VSEPR theory are mentioned below,

TypeofMoleculeNo.ofatomsbondedtocentralatomsNo.oflonepairsoncentralatomArrangementofelectronpairsMolecularGeometryAB220LinearLinearAB330TrigonalplanarTrigonalplanarAB440TetrahedralTetrahedralAB550TrigonalbipyramidalTrigonalbipyramidalAB660OctahedralOctahedral

Explanation of Solution

BeCl2 is a linear molecule which means it is symmetric. And so this molecule is non-polar in nature because the bond dipoles cancel each other.

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: Check whether the given molecule is polar or not. If the molecule is polar then the direction of polarity has to be indicated.

Concept Introduction:

Polar molecules are the molecules having a positive and negative end and so there will be a charge separation.

A polar molecule is a molecule where the polar bonds are asymmetrically arranged (the dipoles do not cancel)

A nonpolar molecule is a molecule with no polar bonds or a molecule where the polar bonds are symmetrically arranged.

In polar molecule the charge separation occurred with respect to the difference in electronegativity of atoms in the molecule.

Direction of dipole moment in a molecule is can be represented as follows,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  2

Different types of molecules and their geometry in accordance with the VSEPR theory are mentioned below,

TypeofMoleculeNo.ofatomsbondedtocentralatomsNo.oflonepairsoncentralatomArrangementofelectronpairsMolecularGeometryAB220LinearLinearAB330TrigonalplanarTrigonalplanarAB440TetrahedralTetrahedralAB550TrigonalbipyramidalTrigonalbipyramidalAB660OctahedralOctahedral

Explanation of Solution

The structure of HBF2 is,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  3

This molecule has a trigonal planar geometry. The fluorine atoms occupied on the negative end of the dipole and the hydrogen atom on the positive end.

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  4

Thus,

HBF2 is an asymmetric molecule. And so this molecule is polar in nature because the bond dipoles do not cancel each other.

(c)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: Check whether the given molecule is polar or not. If the molecule is polar then the direction of polarity has to be indicated.

Concept Introduction:

Polar molecules are the molecules having a positive and negative end (dipole) and so there will be a charge separation.

A polar molecule is a molecule where the polar bonds are asymmetrically arranged (the dipoles do not cancel)

A nonpolar molecule is a molecule with no polar bonds or a molecule where the polar bonds are symmetrically arranged.

In polar molecule the charge separation occurred with respect to the difference in electronegativity of atoms in the molecule.

Direction of dipole in a molecule is can be represented as follows,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  5

Different types of molecules and their geometry in accordance with the VSEPR theory are mentioned below,

TypeofMoleculeNo.ofatomsbondedtocentralatomsNo.oflonepairsoncentralatomArrangementofelectronpairsMolecularGeometryAB220LinearLinearAB330TrigonalplanarTrigonalplanarAB440TetrahedralTetrahedralAB550TrigonalbipyramidalTrigonalbipyramidalAB660OctahedralOctahedral

Explanation of Solution

The structure of CH3Cl is,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  6

This molecule has a tetrahedral geometry. The chlorine atom occupied on the negative end of the dipole and the hydrogen atom on the positive end.

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  7

Thus,

CH3Cl is an asymmetric molecule. And so this molecule is polar in nature because the bond dipoles do not cancel each other.

(d)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: Check whether the given molecule is polar or not. If the molecule is polar then the direction of polarity has to be indicated.

Concept Introduction:

Polar molecules are the molecules having a positive and negative end and so there will be a charge separation.

A polar molecule is a molecule where the polar bonds are asymmetrically arranged (the dipoles do not cancel)

A nonpolar molecule is a molecule with no polar bonds or a molecule where the polar bonds are symmetrically arranged.

In polar molecule the charge separation occurred with respect to the difference in electronegativity of atoms in the molecule.

Direction of dipole moment in a molecule is can be represented as follows,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  8

Different types of molecules and their geometry in accordance with the VSEPR theory are mentioned below,

TypeofMoleculeNo.ofatomsbondedtocentralatomsNo.oflonepairsoncentralatomArrangementofelectronpairsMolecularGeometryAB220LinearLinearAB330TrigonalplanarTrigonalplanarAB440TetrahedralTetrahedralAB550TrigonalbipyramidalTrigonalbipyramidalAB660OctahedralOctahedral

Explanation of Solution

The structure of SO3 is,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  9

This molecule has trigonal planer geometry. The direction dipole moment in the molecule is represented below,

Chemistry & Chemical Reactivity, Chapter 8, Problem 41PS , additional homework tip  10

Thus,

However SO3 an asymmetric molecule it is non- polar in nature because the bond dipoles cancel each other.

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Chapter 8 Solutions

Chemistry & Chemical Reactivity

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