
Concept explainers
Answers to all problems are at the end of this book. Detailed solutions are available in the Student Solutions Manual, Study Guide, and Problems Book.
Drawing Structures of Triacylglycerols Draw the structures of (a) all the possible triacylglycerols that can be formed from glycerol with Stearic and arachidonic acid and (b) all the phosphatidylserine isomers that tan be formed from palmitic and linolenic acids.
(a)

To explain:
The formation from glycerol from stearic and arachidonic acid should be described.
Introduction:
Glycerol is the colorless, viscous liquids that belong to the organic group of alcohol. It has three carbon atoms and three hydroxyl groups in its structure that are known as trihydroxyl sugar alcohol.
Explanation of Solution
The chiral molecule is found in the second carbon of glycerol if there is the presence of different substitutes at both ends of carbon. This can lead to the formation of six triacylglycerols from stearic and arachidonic acids as below:
(b)

To explain:
The formation from phosphatidylserine isomers from palmitic and linolenic acids should be described.
Introduction:
A phospholipid with fatty acid is known as phosphatidylserine that covers and protects the cells in the brain and carries messages. It has two fatty acids attached with ester linkage to the C-1 and C-2 of glycerol and serine attached by a phosphodiester linkage to the C-3 of glycerol.
Explanation of Solution
There is a presence of phosphate bonded with a serine residue at C-3 of glycerol in structures of phosphatidylserine. There are two common forms of linolenic acid which means four different phosphatidylserine can be formed from palmitic and linolenic acids as shown below:
Want to see more full solutions like this?
Chapter 8 Solutions
Study Guide With Student Solutions Manual And Problems Book For Garrett/grisham's Biochemistry, 6th
- In a diffraction experiment of a native crystal, intensity of reflection (-1 0 6) is equivalent to the intensity of reflection (1 0 -6). true or false?arrow_forwardin an x-ray diffraction experiment, moving the detector farther away from the crystal will allow collection of reflection of reflections with high Miller indices. true or false?arrow_forwardShow the mechanism for the acid-catalyzed formation of an [α-1,6] glycosidic linkagebetween two molecules of α-D-glucopyranose.arrow_forward
- Label the following polysaccharide derivatives as reducing or nonreducing. a. C. b. HO CH₂OH CH2OH OH OH OH OH OH HOCH₂ OH OH OH HOCH₂ HO HO HO OH OH ΙΟ CH₂OH OH OH "OH OHarrow_forwardFor a red blood cell (erythrocyte) undergoing active glycolysis, briefly explain how increases in concentration of the following factors are likely to affect glycolytic flux. a. ATP b. AMP c. F-1,6-BP d. F-2,6-BP e. Citrate f. Glucose-6-phosphatearrow_forwardThe ∆G°’ for hydrolysis of phosphoenol pyruvate is -62.2 kJ/mol. The standard freeenergy of ATP hydrolysis is -30.5 kJ/mol. A. What is the standard free energy and K eq of the spontaneous reaction betweenADP/ATP and phosphoenol pyruvate. B. Repeat A for F-1,6-BP (∆G°’=-16.7 kJ/mol) and 1,3-BPG (∆G°’=-49.6 kJ/mol)hydrolysis. C. If the ATP and ADP concentrations are 8mM and 1mM respectively, what would bethe ratio of pyruvate/phosphoenolpyruvate at equilibrium?arrow_forward
- Answerarrow_forward13. Which one is the major organic product of the following sequence of reactions? A OH (CH3)2CHCH2COOH SOCI2 CH3OH 1. CH3MgBr 2. H₂O, H+ B C D OH E OHarrow_forward14. Which one is the major organic product of the following sequence of reactions? (CH3)2CH-COCI CH3OH 1. DIBALH, -78°C 1. PhCH2MgBr ? 2. H2O, HCI 2. H2O, HCI OH OMe A Ph B Ph OH Ph C OMe Ph D E OH .Pharrow_forward
- 6. Which one is the major organic product obtained from the following reaction? CO₂Me 1. LiAlH4 2. H₂O CH₂OH CH₂OCH3 5555 HO A B HO C HO D CH₂OH E ?arrow_forward1. (10 points) Pulverized coal pellets, which may be ° approximated as carbon spheres of radius r = 1 mm, are burned in a pure oxygen atmosphere at 1450 K and 1 atm. Oxygen is transferred to the particle surface by diffusion, where it is consumed in the reaction C + O₂ →> CO₂. The reaction rate is first order and of the form No2 = k₁C₁₂(r), where k₁ = 0.1 m/s. Neglecting changes in r, determine the steady-state O₂ molar consumption rate in kmol/s. At 1450 K, the binary diffusion coefficient for O2 and CO2 is 1.71 x 10ª m²/s.arrow_forward2. (20 points) Consider combustion of hydrogen gas in a mixture of hydrogen and oxygen adjacent to the metal wall of a combustion chamber. Combustion occurs at constant temperature and pressure according to the chemical reaction 2H₂+ O₂→ 2H₂O. Measurements under steady-state conditions at 10 mm from the wall indicate that the molar concentrations of hydrogen, oxygen, and water vapor are 0.10, 0.10, and 0.20 kmol/m³, respectively. The generation rate of water vapor is 0.96x102 kmol/m³s throughout the region of interest. The binary diffusion coefficient for each of the species (H, O̟, and H₂O) in the remaining species is 0.6 X 10-5 m²/s. (a) Determine an expression for and make a qualitative plot of C as a function of distance from the wall. H2 (b) Determine the value of C2 at the wall. H2 (c) On the same coordinates used in part (a), sketch curves for the concentrations of oxygen and water vapor. This will require you to calculate Co, and C. 02 H20 (d) What is the molar flux of water…arrow_forward
- BiochemistryBiochemistryISBN:9781305577206Author:Reginald H. Garrett, Charles M. GrishamPublisher:Cengage Learning
