Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 8, Problem 10E
Give the shape that describes each hybrid orbital set:
(a)
(b)
(c)
(d)
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How is the resonance structure formed to make the following reaction product. Please hand draw the arrows showing how the electrons move to the correct position. Do not use an AI answer. Please draw it yourself or don't bother.
Part II Calculate λ max of the following compounds using wood ward- Fiecer rules
a)
b)
c)
d)
e)
OH
OH
dissolved in dioxane
Br
Br
dissolved in methanol.
NH₂
OCH 3
OH
6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Chapter 8 Solutions
Chemistry (OER)
Ch. 8 - Explain how and bonds are similar and how they...Ch. 8 - Draw a curve that describes the energy of a system...Ch. 8 - Explain why bonds occur at specific average bond...Ch. 8 - Use valence bond theory to explain the bonding in...Ch. 8 - Use valence bond theory to explain the bonding in...Ch. 8 - How many and bonds are present in the molecule...Ch. 8 - A friend tells you N2 has three bonds due to...Ch. 8 - Draw the Lewis structures for CO2 and CO, and...Ch. 8 - Why is the concept of hybridization required in...Ch. 8 - Give the shape that describes each hybrid orbital...
Ch. 8 - Explain why a carbon atom cannot form five bonds...Ch. 8 - What is the hybridization of the central atom in...Ch. 8 - A molecule with the formula AB3 could have one of...Ch. 8 - Methionine, CH3SCH2CH2CH(NH2)CO2H, is an amino...Ch. 8 - Sulfuric acid is manufactured by a series of...Ch. 8 - Two important industrial chemicals, ethene, C2H4,...Ch. 8 - For many years after they were discovered, it was...Ch. 8 - Consider nitrous acid, HNO2 (HONO). (a) Write a...Ch. 8 - Strike-anywhere matches contain a layer of KClO3...Ch. 8 - Identify the hybridization of each carbon atom in...Ch. 8 - Write Lewis structures for NF3 and PP5. On the...Ch. 8 - In addition to NF3, two other fluoro derivatives...Ch. 8 - The bond energy of a C—C single bond averages 347...Ch. 8 - For the carbonate ion, CO32, draw all of the...Ch. 8 - A useful solvent that will dissolve salts as well...Ch. 8 - For the molecule allene, H2C=C=CH2, give the...Ch. 8 - Identify the hybridization of the central atom in...Ch. 8 - Describe the molecular geometry and hybridization...Ch. 8 - For each of the following molecules, indicate the...Ch. 8 - For each of the following structures, determine...Ch. 8 - Draw the orbital diagram for carbon in CO2 showing...Ch. 8 - Sketch the distribution of electron density in the...Ch. 8 - How are the following similar, and how do they...Ch. 8 - If molecular orbitals are created by combining...Ch. 8 - Can a molecule with an odd number of electrons...Ch. 8 - Can a molecule with an even number of electrons...Ch. 8 - Why are bonding molecular orbitals lower in energy...Ch. 8 - Calculate the bond order for an ion with this...Ch. 8 - Explain why an electron in the bonding molecular...Ch. 8 - Predict the valence electron molecular orbital...Ch. 8 - Determine the bond order of each member of the...Ch. 8 - For the first ionization energy for an N2...Ch. 8 - Compare the atomic and molecular orbital diagrams...Ch. 8 - Which of the period 2 homonuclear diatomic...Ch. 8 - A friend tells you that the 2s orbital for...Ch. 8 - True or false: Boron contains 2s22p1 valence...Ch. 8 - What charge would be needed on F2 to generate an...Ch. 8 - Predict whether the MO diagram S2 would show s-p...Ch. 8 - Explain why N22+ is diamagnetic, while O24+, which...Ch. 8 - Using the MO diagrams, predict the bond order for...
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- Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.arrow_forwardPart II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1arrow_forwardAE>AE₁ (Y/N) AE=AE₁ (Y/N) AEarrow_forwardTreatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br Aarrow_forwardCorrectly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν Harrow_forwardHow is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.arrow_forwardPart VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?arrow_forwardDon't used Ai solutionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward↑ 0 Quiz List - RCC430M_RU05 X Aktiv Learning App × Qdraw resonance structure ×Q draw resonance structure xb My Questions | bartleby ×+ https://app.aktiv.com Draw a resonance structure of pyrrole that has the same number of pi bonds as the original structure. Include all lone pairs in your structure. + N H a 5 19°F Cloudy Q Search Problem 12 of 15 Atoms, Bonds and Rings Charges and Lone Pairs myhp हजु Undo Reset Remove Done Submit Drag To Pan 2:15 PM 1/25/2025arrow_forwardDon't used hand raitingarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
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