Major and minor product should be drawn for the given substrates during E2 elimination reaction. Concept Introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E 1 and E 2 . E 1 reaction: elimination follows stepwise mechanism. E 2 reaction: elimination follows concerted pathway of mechanism. Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene.

Question

Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 31 0.5 30 26 29 22 28 100 27 33 26 23 15 4 • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. 妊 n ? Previous Next

Answer 1

Question

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 31 0.5 30 26 29 22 28 100 27 33 26 23 15 4 • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. 妊 n ? Previous Next

for this question. Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 98.1106. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)

PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS!!! PLEASE I UNDERSTAND THE BASICS BUT THIS IS AN EXCEPTION THAT EVEN THE INTERNET CANT HELP!!!! THIS IS THE THIRD TIME I'VE SENT THOSE QUESTIONS SO PLEASE DONT RESEND THE SAME STUFF, ITS NOT HELPING ME!!! I ALSO ALREADY TRIED TO DRAW THE MECHANISM MYSELF, SO IF ITS RIGHT PLEASE TELL ME OR TELL ME WHAT I HAVE TO CHANGE!!! First image: I have to SHOW (DRAWING) the mechanism (with arows and structures of molecules) NOT WORDS PLEASE! of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary Second image: I have to show the mechanism (IMAGE) (with arrows and structures of the molecules) NOT WORDS PLEASE !! for the reaction on the left, where the alcohol A is added fast in one portion HOMEWORK, NOT EXAM!! ALL DETAILS ARE IN THE IMAGES PLEASE LOOK AT THE IMAGES, DONT LOOK AT THE AI GENERATED TEXT!!!

Answer 2

Question

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 3

Question

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 4

Question

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 5

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 6

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 7

Chapter 7.8, Problem 21PTS

(a)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 8

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 9

(b)

Interpretation Introduction

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 18

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 19

(g)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 20

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 21

(h)

Interpretation Introduction

Interpretation:

Major and minor product should be drawn for the given substrates during E2 elimination reaction.

Concept Introduction:

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, $E1$ and $E2$ .

$E1$ reaction: elimination follows stepwise mechanism.

$E2$ reaction: elimination follows concerted pathway of mechanism.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 22

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Answer 23

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Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

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