The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given. Concept Introduction: Addition of halides to alkynes : Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below. If excess halides are present, a second addition reaction also occurs.

Question

Which of the following is true for a particular reaction if ∆G° is -40.0 kJ/mol at 290 K and –20.0 kJ/mol at 390 K?

Answer 1

Question

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 2

Question

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 3

Question

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 4

Question

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 5

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 6

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 7

Chapter 7.6, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The mechanism for the reaction of 2-butyne with one equivalent of bromine should be given.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The configuration of the product obtained in the above reaction should be identified.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 10

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Answer 21

Ch. 7.1 - What is the molecular formula for a monocyclic...Ch. 7.1 - Prob. 2P Ch. 7.1 - Draw the structure and give the common and...Ch. 7.1 - Prob. 4P Ch. 7.1 - Name the following:Ch. 7.2 - Prob. 6P Ch. 7.2 - Name the following:Ch. 7.3 - Prob. 8P Ch. 7.3 - Why does cis-2-butene have a higher boiling point...Ch. 7.4 - What orbitals are used to form the carbon-carbon ...

Solution Summary: The author explains the mechanism for the reaction of 2-butyne with one equivalent of bromine.

Chapter 7 Solutions