The mechanism for reaction between benzene and given electrophile should be identified. Concept Introduction: Mechanism for electrophilic aromatic substitution is as follows, 1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate. 2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

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Answer 1

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Answer 3

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Answer 4

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Answer 5

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 6

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 7

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.4 - Prob. 1P Ch. 7.5 - Prob. 3P Ch. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5P Ch. 7.6 - Prob. 6P Ch. 7.7 - Prob. 7P Ch. 7.7 - Prob. 8P Ch. 7.7 - Prob. 9P Ch. 7.7 - Prob. 10P Ch. 7.8 - Which member of each pair is the stronger acid? a....

Solution Summary: The author explains the mechanism for reaction between benzene and given electrophile.

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