The mechanism for reaction between benzene and given electrophile should be identified. Concept Introduction: Mechanism for electrophilic aromatic substitution is as follows, 1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate. 2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

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Answer 1

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H H

H H (1) H C. C C .H (2) (3) Cl H The ideal value for bond angle (1) is (Choose one) and the ideal value for bond angle (3) is (Choose one) degrees, the value for bond angle (2) is (Choose one) degrees, degrees.

Answer 2

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Answer 3

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Answer 4

Question

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

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Answer 5

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 6

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 7

Chapter 7.17, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1. First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2. The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate which then electrons again move into the ring regaining its aromaticity.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The mechanism for reaction between benzene and given electrophile should be identified.

Concept Introduction:

Mechanism for electrophilic aromatic substitution is as follows,

1 First, electrophile gets added to the carbon–carbon double bond in benzene which then results to form carbocation intermediate.

2 The base removes the proton present in carbocation intermediate in which electrons present in C-H bond again moves into the ring regaining its aromaticity results in the formation of product.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.4 - Prob. 1P Ch. 7.5 - Prob. 3P Ch. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5P Ch. 7.6 - Prob. 6P Ch. 7.7 - Prob. 7P Ch. 7.7 - Prob. 8P Ch. 7.7 - Prob. 9P Ch. 7.7 - Prob. 10P Ch. 7.8 - Which member of each pair is the stronger acid? a....

Solution Summary: The author explains the mechanism for reaction between benzene and given electrophile.

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