The products of the given reaction have to be given. Concept Introduction: Addition of hydrogen halides to alkenes : Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon ( Markovnikov's rule ).

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Answer 1

Question

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H H

H H (1) H C. C C .H (2) (3) Cl H The ideal value for bond angle (1) is (Choose one) and the ideal value for bond angle (3) is (Choose one) degrees, the value for bond angle (2) is (Choose one) degrees, degrees.

Answer 2

Question

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

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Answer 3

Question

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

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Answer 4

Question

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

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Answer 5

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 6

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 7

Chapter 7.11, Problem 19P

(a)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic addition to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of water across double bond:

Alcohols can be prepared from alkenes by heating with water in the presence of an acid catalyst and the process is called hydration of alkenes.

Across the double bond, water addition occurs.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The products of the given reaction have to be given.

Concept Introduction:

Addition of hydrogen halides to alkenes:

Addition of hydrogen halides to alkenes is one of the electrophilic additions to yield the corresponding halo alkanes. In this reaction the halide ion adds to the double bond carbon which is having lesser number of hydrogen or more substituted carbon (Markovnikov's rule).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.4 - Prob. 1P Ch. 7.5 - Prob. 3P Ch. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5P Ch. 7.6 - Prob. 6P Ch. 7.7 - Prob. 7P Ch. 7.7 - Prob. 8P Ch. 7.7 - Prob. 9P Ch. 7.7 - Prob. 10P Ch. 7.8 - Which member of each pair is the stronger acid? a....

Solution Summary: The author explains the electrophilic addition of hydrogen halides to alkenes. The proton is added to C-1 of the conjugated system, leading to the formation of an ally

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