Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)
Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134649771
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

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Chapter 7 Solutions

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)

Ch. 7.6 - Prob. 12PCh. 7.6 - Prob. 13PCh. 7.7 - Prob. 14PCh. 7.7 - Which alkyne should be used for the synthesis of...Ch. 7.7 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.8 - Only one alkyne forms an aldehyde when it...Ch. 7.9 - Describe the alkyne you should start with and the...Ch. 7.9 - Prob. 20PCh. 7.10 - Prob. 21PCh. 7.10 - Prob. 22PCh. 7.10 - Prob. 23PCh. 7.10 - Rank the following from strongest base to weakest...Ch. 7.10 - Prob. 26PCh. 7.12 - Prob. 28PCh. 7 - What is the major product obtained from the...Ch. 7 - Draw a condensed structure for each of the...Ch. 7 - A student was given the structural formula of...Ch. 7 - Prob. 32PCh. 7 - What is each compounds systematic name?Ch. 7 - What reagents should be used to carry out the...Ch. 7 - Prob. 35PCh. 7 - Draw the mechanism for the following reaction:Ch. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - What is the major product of the reaction of 1 mol...Ch. 7 - Answer Problem 39, parts a-b, using 2-butyne as...Ch. 7 - What is each compounds systematic name? a....Ch. 7 - What is the molecular formula of a hydrocarbon...Ch. 7 - a. Starting with 3-methyl 1-butyne, how can you...Ch. 7 - Prob. 44PCh. 7 - Which of the following pairs are keto-enol...Ch. 7 - Prob. 46PCh. 7 - Do the equilibria of the following acid-base...Ch. 7 - What is each compounds systematic name?Ch. 7 - What stereoisomers are obtained when 2-butyne...Ch. 7 - Prob. 50PCh. 7 - Draw the keto tautomer for each of the following:Ch. 7 - Show how each of the following compounds can be...Ch. 7 - A chemist is planning to synthesize 3-octyne by...Ch. 7 - Prob. 54PCh. 7 - What stereoisomers are obtained from the following...Ch. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Show how the following compound can be prepared...Ch. 7 - Prob. 60P
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