The name of the given alkyne should be identified. Concept Introduction: IUPAC NOMENCLATURE RULES: If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained. Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group . Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain. When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

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Answer 1

Question

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Propose a synthesis pathway for the following transformations. b) c) d)

Answer 2

Question

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

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Answer 3

Question

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

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See solution

Answer 4

Question

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Expert Solution & Answer

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Answer 5

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 6

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 7

Chapter 7.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The name of the given alkyne should be identified.

Concept Introduction:

NOMENCLATURE RULES:

If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.

Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.

Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.

When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.1 - Prob. 1P Ch. 7.1 - Name the following:Ch. 7.1 - What is the molecular formula for a monocyclic...Ch. 7.1 - Draw the condensed and skeletal structures for...Ch. 7.1 - Draw the structure and give the common and...Ch. 7.2 - Prob. 6P Ch. 7.2 - Name the following:Ch. 7.3 - What orbitals are used to form the carbon-carbon ...Ch. 7.4 - Prob. 9P Ch. 7.4 - Why does cis-2-butene have a higher boiling point...

Solution Summary: The author explains that the name of the given alkyne should be identified by selecting the longest chain which contains the triple bond to get lowest value for the functional group.

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Chapter 7 Solutions