Introduction to Chemistry
Introduction to Chemistry
4th Edition
ISBN: 9780073523002
Author: Rich Bauer, James Birk Professor Dr., Pamela S. Marks
Publisher: McGraw-Hill Education
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Chapter 7, Problem 98QP
Interpretation Introduction

Interpretation:

Whether potassium or calcium has higher second ionization enthalpy is to bde identified.

Concept Introduction:

The second ionization energy is higher than the first ionization energy as the electron has to be removed from a positively charged ion. The nucleus holds core electrons strongly compared to valence electrons and therefore ionization enthalpy of core electrons is very high.

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Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.  (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ­ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
5. The atoms and ions Ne, N³-, F, Mg2+, and Si4+ are part of an isoelectronic series. (a) Which of these will have the smallest effective nuclear charge acting on the outermost electron? (b) Which one possess the greatest effective nuclear charge? (c) Which ion will be the largest in size? Explain why.

Chapter 7 Solutions

Introduction to Chemistry

Ch. 7 - Prob. 4PPCh. 7 - Prob. 5PPCh. 7 - Prob. 6PPCh. 7 - Prob. 7PPCh. 7 - Prob. 8PPCh. 7 - Prob. 9PPCh. 7 - Prob. 10PPCh. 7 - Prob. 11PPCh. 7 - Prob. 1QPCh. 7 - Match the key terms with the descriptions...Ch. 7 - Prob. 3QPCh. 7 - Prob. 4QPCh. 7 - Prob. 5QPCh. 7 - Prob. 6QPCh. 7 - Prob. 7QPCh. 7 - Prob. 8QPCh. 7 - Prob. 9QPCh. 7 - Prob. 10QPCh. 7 - Prob. 11QPCh. 7 - Prob. 12QPCh. 7 - Prob. 13QPCh. 7 - Prob. 14QPCh. 7 - Prob. 15QPCh. 7 - Prob. 16QPCh. 7 - Prob. 17QPCh. 7 - Prob. 18QPCh. 7 - Prob. 19QPCh. 7 - Prob. 20QPCh. 7 - Prob. 21QPCh. 7 - Prob. 22QPCh. 7 - Bohr proposed that the electron in a hydrogen atom...Ch. 7 - Prob. 24QPCh. 7 - Prob. 25QPCh. 7 - Prob. 26QPCh. 7 - Prob. 27QPCh. 7 - Prob. 28QPCh. 7 - Prob. 29QPCh. 7 - Prob. 30QPCh. 7 - Prob. 31QPCh. 7 - In the Bohr model, which of the following electron...Ch. 7 - Prob. 33QPCh. 7 - Prob. 34QPCh. 7 - Prob. 35QPCh. 7 - Prob. 36QPCh. 7 - Prob. 37QPCh. 7 - Prob. 38QPCh. 7 - Prob. 39QPCh. 7 - Prob. 40QPCh. 7 - Prob. 41QPCh. 7 - Prob. 42QPCh. 7 - Prob. 43QPCh. 7 - Prob. 44QPCh. 7 - Prob. 45QPCh. 7 - Complete the following orbital diagrams for the...Ch. 7 - Prob. 47QPCh. 7 - Prob. 48QPCh. 7 - Prob. 49QPCh. 7 - Prob. 50QPCh. 7 - Prob. 51QPCh. 7 - Prob. 52QPCh. 7 - Prob. 53QPCh. 7 - Prob. 54QPCh. 7 - Prob. 55QPCh. 7 - Prob. 56QPCh. 7 - Prob. 57QPCh. 7 - Prob. 58QPCh. 7 - Prob. 59QPCh. 7 - Prob. 60QPCh. 7 - Prob. 61QPCh. 7 - Prob. 62QPCh. 7 - Prob. 63QPCh. 7 - Prob. 64QPCh. 7 - Prob. 65QPCh. 7 - Prob. 66QPCh. 7 - Prob. 67QPCh. 7 - Prob. 68QPCh. 7 - Prob. 69QPCh. 7 - Prob. 70QPCh. 7 - Prob. 71QPCh. 7 - Prob. 72QPCh. 7 - Prob. 73QPCh. 7 - Prob. 74QPCh. 7 - Prob. 75QPCh. 7 - Prob. 76QPCh. 7 - Prob. 77QPCh. 7 - Prob. 78QPCh. 7 - Prob. 79QPCh. 7 - Prob. 80QPCh. 7 - Prob. 81QPCh. 7 - Write the complete and abbreviated electron...Ch. 7 - Prob. 83QPCh. 7 - Prob. 84QPCh. 7 - Prob. 85QPCh. 7 - Prob. 86QPCh. 7 - Prob. 87QPCh. 7 - Prob. 88QPCh. 7 - Prob. 89QPCh. 7 - Prob. 90QPCh. 7 - Prob. 91QPCh. 7 - Prob. 92QPCh. 7 - Prob. 93QPCh. 7 - Prob. 94QPCh. 7 - Prob. 95QPCh. 7 - Prob. 96QPCh. 7 - Prob. 97QPCh. 7 - Prob. 98QPCh. 7 - Prob. 99QPCh. 7 - Prob. 100QPCh. 7 - Prob. 101QPCh. 7 - Prob. 102QPCh. 7 - Prob. 103QPCh. 7 - Prob. 104QPCh. 7 - Prob. 105QPCh. 7 - Prob. 106QPCh. 7 - Which is the larger ion, K+orCa2+? Explain.Ch. 7 - Prob. 108QPCh. 7 - Prob. 109QPCh. 7 - Prob. 110QPCh. 7 - Prob. 111QPCh. 7 - Prob. 112QPCh. 7 - Prob. 113QPCh. 7 - Prob. 114QPCh. 7 - Prob. 115QPCh. 7 - Prob. 116QPCh. 7 - Prob. 117QPCh. 7 - Prob. 118QPCh. 7 - Prob. 119QPCh. 7 - Prob. 120QPCh. 7 - Prob. 121QPCh. 7 - Prob. 122QPCh. 7 - Prob. 123QPCh. 7 - Prob. 124QPCh. 7 - Prob. 125QPCh. 7 - Prob. 126QPCh. 7 - Prob. 127QPCh. 7 - Prob. 128QPCh. 7 - Prob. 129QPCh. 7 - Prob. 130QPCh. 7 - Prob. 131QPCh. 7 - Prob. 132QPCh. 7 - Prob. 133QPCh. 7 - How many unpaired electrons are in a single atom...Ch. 7 - Prob. 135QPCh. 7 - Which element has a ground-state electron...Ch. 7 - Which of the following is the correct abbreviated...Ch. 7 - Prob. 138QPCh. 7 - Prob. 139QPCh. 7 - Prob. 140QPCh. 7 - Prob. 141QPCh. 7 - Prob. 142QP
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