Concept explainers
(a)
Interpretation:
The given electron transition in the hydrogen atom leads to the emission of light with the longest wavelength or not and whether it has the greatest photon energy or not is to be determined.
(b)
Interpretation:
The given electron transition in the hydrogen atom leads to the emission of light with the longest wavelength or not and whether it has the greatest photon energy or not is to be determined.
(c)
Interpretation:
The given electron transition in the hydrogen atom leads to the emission of light with the longest wavelength or not and whether it has the greatest photon energy or not is to be determined.
(d)
Interpretation:
The given electron transition in the hydrogen atom leads to the emission of light with the longest wavelength or not and whether it has the greatest photon energy or not is to be determined.
(e)
Interpretation:
Whether all the given transitions will result in the emission of light of the same wavelength or not is to be determined.
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Chapter 7 Solutions
Introduction to Chemistry
- 6.29 A mercury atom emits light at many wavelengths, two of which are at 435.8 and 546.1 nm. Both of these transitions are to the same final state. (a) What is the energy difference between the two states for each transition? (b) lf a transition between the two higher energy states could be observed, what would be the frequency of the light?arrow_forward(a) Give the complete electron configuration (1s22s22p) of aluminum in the ground state. (b) The wavelength of the radiation emitted when the outermost electron of aluminum falls from the 4s state to the ground state is about 395 nm. Calculate the energy separation (in joules) between these two states in the Al atom. (c) When the outermost electron in aluminum falls from the 3d state to the ground state, the radiation emitted has a wavelength of about 310 nm. Draw an energylevel diagram of the states and transitions discussed here and in (b). Calculate the separation (in joules) between the 3d and 4s states in aluminum. Indicate clearly which has higher energy.arrow_forwardAs the weapons officer aboard the Srarship Chemistry, it is your duty to configure a photon torpedo to remove an electron from the outer hull of an enemy vessel. You know that the work function (the binding energy of the electron) of the hull of the enemy ship is 7.52 1019 J. a. What wavelength does your photon torpedo need to be to eject an electron? b. You find an extra photon torpedo with a wavelength of 259 nm and fire it at the enemy vessel. Does this photon torpedo do any damage to the ship (does it eject an electron)? c. If the hull of the enemy vessel is made of the element with an electron configura tion of [Ar]4s13d10, what metal is this?arrow_forward
- 6.93 A mercury atom is initially in its lowest possible (or ground state) energy level. The atom absorbs a photon with a wavelength of 185 nm and then emits a photon with a frequency of 4.9241014HZ . At the end of this series of transitions, the atom will still be in an energy level above the ground state. Draw an energy-level diagram for this process and find the energy of this resulting excited state, assuming that we assign a value of E = 0 to the ground state. (This choice of E = 0 is not the usual convention, but it will simplify the calculations you need to do here.)arrow_forwardWhich of the following statements is (are) true? I. The product of wavelength and frequency of light is a constant. II. As the energy of electromagnetic radiation increases, its frequency decreases. III. As the wavelength of light increases, its frequency increases. a I only b II only c III only d I and III only e II and III onlyarrow_forwardWarm objects emit electromagnetic radiation in the infrared region. Heat lamps employ this principle to generate infrared radiation. Water absorbs infrared radiation with wavelengths near 2.80 m. Suppose this radiation is absorbed by the water and converted to heat. A 1.00-L sample of water absorbs infrared radiation, and its temperature increases from 20.0C to 30.0C. How many photons of this radiation are used to heat the water?arrow_forward
- Given the following energy level diagram for an atom that contains an electron in the n = 3 level, answer the following questions. a Which transition of the electron will emit light of the lowest frequency? b Using only those levels depicted in the diagram, which transition of the electron would require the highest-frequency light? c If the transition from the n = 3 level to the n = 1 level emits green light, what color light is absorbed when an electron makes the transition from the n = 1 to n = 3 level?arrow_forward6.28 A neon atom cmi light at many wavelengths, two of which are at 616.4 and 638.3 nm. Both of these transitions are to the same final state. (a) What is the energy difference between the two states for each transition? (b) If a transition between the two higher energy states could be observed, what would be the frequency of the light?arrow_forwardA hydrogen atom in the ground stale absorbs a photon whose wavelength is 95.0 nm. The resulting excited atom then emits a photon of 1282 nm. What are the regions of the electromagnetic spectrum for the radiations involved in these transitions? What is the principal quantum number of the final state resulting from the emission from the excited atom?arrow_forward
- Heated lithium atoms emit photons of light with an energy of 2.9611019 J. Calculate the frequency and wavelength of one of these photons. What is the total energy in 1 mole of these photons? What is the color of the emitted light?arrow_forwardWhat are the allowed values for each of the four quantum numbers: n, l, ml, and ms?arrow_forwardRGB color television and computer displays use cathode ray tubes that produce colors by mixing red, green, and blue light. If we look at the screen with a magnifying glass, we can see individual dots turn on and off as the colors change. Using a spectrum of visible light, determine the approximate wavelength of each of these colors. What is the frequency and energy of a photon of each of these colors?arrow_forward
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