Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 7, Problem 93AP
Interpretation Introduction
Interpretation:
Reaction occurred between metal and oxygen.
Concept Introduction:
Corrosion is the process in which metals decays when its surface is exposed to gases and liquids. This process is called oxidation in which compound gains oxygen atom.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 7 Solutions
Introductory Chemistry: A Foundation
Ch. 7.2 - at if no ionic solids were soluble in water? Could...Ch. 7.2 - Prob. 7.1SCCh. 7.3 - trong>Exercise 7.2 For each of the following...Ch. 7.5 - Prob. 7.3SCCh. 7.7 - lton believed that atoms were indivisible. Thomson...Ch. 7.7 - ercise 7.4 Classify each of the following...Ch. 7 - onsider the mixing of aqueous solutions of...Ch. 7 - ssume a highly magnified view of a solution of HCI...Ch. 7 - hy is the formation of a solid evidence of a...Ch. 7 - Prob. 4ALQ
Ch. 7 - ixing an aqueous solution of potassium nitrate...Ch. 7 - Prob. 6ALQCh. 7 - se the Arrhenius definition of acids and bases to...Ch. 7 - Prob. 8ALQCh. 7 - hy is the formation of a gas evidence of a...Ch. 7 - Label each of the following statements as true or...Ch. 7 - Look at Fig. 7.2 in the text. It is possible for a...Ch. 7 - What is the purpose of spectator ions? If they are...Ch. 7 - Which of the following must be an...Ch. 7 - If an element is a reactant or product in a...Ch. 7 - Prob. 15ALQCh. 7 - On the basis of the general solubility rules given...Ch. 7 - Write the balanced formula and net ionic equation...Ch. 7 - hy is water an important solvent? Although you...Ch. 7 - hat is a “driving force”? What are some of the...Ch. 7 - Prob. 3QAPCh. 7 - Prob. 4QAPCh. 7 - escribe briefly what happens when an ionic...Ch. 7 - hen the ionic solute K3PO4is dissolved in water,...Ch. 7 - Prob. 7QAPCh. 7 - ow do chemists know that the ions behave...Ch. 7 - uppose you are trying to help your friend...Ch. 7 - Using the general solubility rules given in Table...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - Prob. 16QAPCh. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - Balance each of the following equations that...Ch. 7 - Balance each of the following equations that...Ch. 7 - For each of the following precipitation reactions,...Ch. 7 - A solution of zinc nitrate is mixed with a...Ch. 7 - What is a net ionic equation? What species are...Ch. 7 - Prob. 24QAPCh. 7 - Based on the general solubility rules given in...Ch. 7 - Write the balanced molecular, complete ionic, and...Ch. 7 - Many chromate salts are insoluble, and most have...Ch. 7 - The procedures and principles of qualitative...Ch. 7 - Many plants are poisonous because their stems and...Ch. 7 - Prob. 30QAPCh. 7 - What is meant by a strong acid? Are the strong...Ch. 7 - What is meant by a strong base? Are the strong...Ch. 7 - The same net ionic process takes place when any...Ch. 7 - Prob. 34QAPCh. 7 - If 1000 NaOH units were dissolved in a sample of...Ch. 7 - What is a salt? Give two balanced chemical...Ch. 7 - Write balanced equations showing how three of the...Ch. 7 - Prob. 38QAPCh. 7 - What salt would form when each of the following...Ch. 7 - Prob. 40QAPCh. 7 - Prob. 41QAPCh. 7 - Give an example of a simple chemical reaction that...Ch. 7 - What do we mean when we say that the transfer of...Ch. 7 - Prob. 44QAPCh. 7 - If atoms of the metal calcium were to react with...Ch. 7 - If oxygen molecules, were to react with magnesium...Ch. 7 - Prob. 47QAPCh. 7 - Prob. 48QAPCh. 7 - Prob. 49QAPCh. 7 - Prob. 50QAPCh. 7 - Prob. 51QAPCh. 7 - The reaction between ammonium perchlorate and...Ch. 7 - Identify each of the following unbalanced reaction...Ch. 7 - Prob. 54QAPCh. 7 - Prob. 55QAPCh. 7 - Prob. 56QAPCh. 7 - What is a synthesis or combination reaction? Give...Ch. 7 - What is a decomposition reaction? Give an example....Ch. 7 - Complete and balance each of the following...Ch. 7 - Prob. 60QAPCh. 7 - Prob. 61QAPCh. 7 - Prob. 62QAPCh. 7 - Balance each of the following equations that...Ch. 7 - Prob. 64QAPCh. 7 - Balance each of the following equations that...Ch. 7 - Prob. 66QAPCh. 7 - Distinguish between the molecular equation, the...Ch. 7 - Prob. 68APCh. 7 - Without first writing a full molecular or ionic...Ch. 7 - Complete and balance each of the following...Ch. 7 - Prob. 71APCh. 7 - Prob. 72APCh. 7 - Prob. 73APCh. 7 - Prob. 74APCh. 7 - For each of the following unbalanced molecular...Ch. 7 - Write the balanced molecular, complete ionic, and...Ch. 7 - What strong acid and what strong base would react...Ch. 7 - Prob. 78APCh. 7 - For the reaction 16Fe(s)+3S8(s)8Fe2S3(s), show how...Ch. 7 - Prob. 80APCh. 7 - Identify each of the following unbalanced reaction...Ch. 7 - Which of the following statements is/are true...Ch. 7 - Prob. 83APCh. 7 - Prob. 84APCh. 7 - Prob. 85APCh. 7 - Prob. 86APCh. 7 - Prob. 87APCh. 7 - For each of the following metals, how many...Ch. 7 - For each of the following nonmetals, how many...Ch. 7 - True or false? When solutions of barium hydroxide...Ch. 7 - Classify the reactions represented by the...Ch. 7 - When a sodium chromate solution and aluminum...Ch. 7 - Prob. 93APCh. 7 - Consider a solution with the following ions...Ch. 7 - Prob. 95APCh. 7 - For the following chemical reactions, determine...Ch. 7 - Prob. 97CPCh. 7 - hat kind of visual evidence indicates that a...Ch. 7 - Prob. 2CRCh. 7 - Prob. 3CRCh. 7 - Prob. 4CRCh. 7 - hat is meant by the driving force for a reaction?...Ch. 7 - xplain to your friend what chemists mean by a...Ch. 7 - efine the term strong electrolyte. What types of...Ch. 7 - ummarize the simple solubility rules for ionic...Ch. 7 - n general terms, what are the spectator ions in a...Ch. 7 - Describe some physical and chemical properties of...Ch. 7 - Prob. 11CRCh. 7 - What do we call reactions in which electrons are...Ch. 7 - What is a combustion reaction? Are combustion...Ch. 7 - Prob. 14CRCh. 7 - List and define all the ways of classifying...Ch. 7 - The element carbon undergoes many inorganic...Ch. 7 - Prob. 17CRCh. 7 - The reagent shelf in a general chemistry lab...Ch. 7 - Prob. 19CRCh. 7 - Prob. 20CRCh. 7 - Prob. 21CRCh. 7 - Prob. 22CRCh. 7 - Using the general solubility rules discussed in...Ch. 7 - Write the balanced net ionic equation for the...Ch. 7 - Prob. 25CR
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