Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162430
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 7, Problem 91E
Interpretation Introduction
To determine: The wavelength.
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Calculate the atomic packing factor of quartz, knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.
3.
a. Use the periodic table to add up the molecular weight of thionyl chloride (SOCl2) and show your work.
b. The actual value obtained for the molecular ion on a high resolution mass spectrometer is 117.9041.
Explain the discrepancy.
c. Show the calculations that correctly result in the exact mass of 117.9041 for SOC₁₂. Use Table 11.2 or
Appendix E in your calculations.
6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
B₂2+
B22+, B2, C22, B22- and N22+
Molecular Orbital Diagram
B2
C22-
B22-
N22+
Which molecule is paramagnetic?
Chapter 7 Solutions
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Ch. 7 - Which wavelength of light has the highest...Ch. 7 - Q2. Which kind of electromagnetic radiation...Ch. 7 - Q3. How much energy (in J) is contained in 1.00...Ch. 7 - Q4. Light from three different lasers (A, B, and...Ch. 7 - Prob. 5SAQCh. 7 - Prob. 6SAQCh. 7 - Prob. 7SAQCh. 7 - Prob. 8SAQCh. 7 - Prob. 9SAQCh. 7 - Prob. 10SAQ
Ch. 7 - 1. Why is the quantum mechanical model of the atom...Ch. 7 - Prob. 2ECh. 7 - 3. Define the wavelength and amplitude of a wave....Ch. 7 - 4. Define the frequency of electromagnetic...Ch. 7 - 5. What determines the color of light? Describe...Ch. 7 - Prob. 6ECh. 7 - Prob. 7ECh. 7 - Prob. 8ECh. 7 - Prob. 9ECh. 7 - 10. Describe the photoelectric effect. How did...Ch. 7 - Prob. 11ECh. 7 - 12. What is a photon? How is the energy of a...Ch. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Prob. 16ECh. 7 - 17. What are complementary properties? How does...Ch. 7 - Prob. 18ECh. 7 - 19. What is a trajectory? What kind of information...Ch. 7 - Prob. 20ECh. 7 - 21. Newton’s laws of motion are deterministic....Ch. 7 - Prob. 22ECh. 7 - 23. What is a probability distribution map?
Ch. 7 - 24. For each solution to the Schrödinger equation,...Ch. 7 - Prob. 25ECh. 7 - 26. What is the Schrödinger equation? What is a...Ch. 7 - 27. What are the possible values of the principal...Ch. 7 - 28. What are the possible values of the angular...Ch. 7 - 29. What are the possible values of the magnetic...Ch. 7 - 30. List all the orbitals in each principal level....Ch. 7 - 31. Explain the difference between a plot showing...Ch. 7 - 32. Make sketches of the general shapes of the s,...Ch. 7 - Prob. 33ECh. 7 - 34. Why are atoms usually portrayed as spheres...Ch. 7 - 35. The distance from the sun to Earth is km. How...Ch. 7 - Prob. 36ECh. 7 - 37. List these types of electromagnetic radiation...Ch. 7 - 38. List these types of electromagnetic radiation...Ch. 7 - 39. Calculate the frequency of each wavelength of...Ch. 7 - Prob. 40ECh. 7 - 41. Calculate the energy of a photon of...Ch. 7 - 42. Calculate the energy of a photon of...Ch. 7 - 43. A laser pulse with wavelength 532 nm contains...Ch. 7 - Prob. 44ECh. 7 - 45. Determine the energy of 1 mol of photons for...Ch. 7 - 46. How much energy is contained in 1 mol of...Ch. 7 - Prob. 47ECh. 7 - Prob. 48ECh. 7 - Prob. 49ECh. 7 - 50. The smallest atoms can themselves exhibit...Ch. 7 - 51. What is the de Broglie wavelength of an...Ch. 7 - 52. A proton in a linear accelerator has a de...Ch. 7 - 53. Calculate the de Broglie wavelength of a 143-g...Ch. 7 - 54. A 0.22-caliber handgun fires a 1.9-g bullet at...Ch. 7 - 55. An electron has an uncertainty in its position...Ch. 7 - 56. An electron traveling at 3.7 × 105 m/s has an...Ch. 7 - 57. Which electron is, on average, closer to the...Ch. 7 - Prob. 58ECh. 7 - 59. What are the possible values of l for each...Ch. 7 - Prob. 60ECh. 7 - 61. Which set of quantum numbers cannot specify an...Ch. 7 - 62. Which combinations of n and l represent real...Ch. 7 - 63. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 7 - Prob. 64ECh. 7 - 65. An electron in a hydrogen atom is excited with...Ch. 7 - 66. Determine whether each transition in the...Ch. 7 - 67. According to the quantum-mechanical model for...Ch. 7 - 68. According to the quantum-mechanical model for...Ch. 7 - 69. Calculate the wavelength of the light emitted...Ch. 7 - 70. Calculate the frequency of the light emitted...Ch. 7 - 71. An electron in the n = 7 level of the hydrogen...Ch. 7 - Prob. 72ECh. 7 - 73. Ultraviolet radiation and radiation of shorter...Ch. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - 76. A green leaf has a surface area of 2.50 cm2....Ch. 7 - 77. In a technique used for surface analysis...Ch. 7 - Prob. 78ECh. 7 - Prob. 79ECh. 7 - 80. The energy required to ionize sodium is 496...Ch. 7 - Prob. 81ECh. 7 - 82. Suppose that, in an alternate universe, the...Ch. 7 - Prob. 83ECh. 7 - Prob. 84ECh. 7 - 85. The binding energy of electrons in a metal is...Ch. 7 - 86. In order for a thermonuclear fusion reaction...Ch. 7 - Prob. 87ECh. 7 - 88. The distance from Earth to the sun is 1.5 ×...Ch. 7 - 89. The iodine molecule can be photodissociated...Ch. 7 - 90. A 5.00-mL ampule of a 0.100-M solution of...Ch. 7 - 91. A laser produces 20.0 mW of red light. In 1.00...Ch. 7 - Prob. 92ECh. 7 - 93. The quantum yield of light-induced chemical...Ch. 7 - Prob. 94ECh. 7 - Prob. 95ECh. 7 - Prob. 96ECh. 7 - Prob. 97ECh. 7 - Prob. 98ECh. 7 - 99. Find the velocity of an electron emitted by a...Ch. 7 - 100. Water is exposed to infrared radiation of...Ch. 7 - 101. The 2005 Nobel Prize in Physics was given, in...Ch. 7 - 102. A metal with a threshold frequency of 6.71 ×...Ch. 7 - Prob. 103ECh. 7 - Prob. 104ECh. 7 - 105. Explain the difference between the Bohr model...Ch. 7 - 106. The light emitted from one of the following...Ch. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Discuss the nature of light with your group....Ch. 7 - Prob. 110QGWCh. 7 - Prob. 111QGWCh. 7 - Prob. 112QGWCh. 7 - Prob. 113QGWCh. 7 - 114. On average sunlight shines on the surface of...
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