OWLv2 for Oxtoby/Gillis/Butler's Principles of Modern Chemistry, 8th Edition, [Instant Access], 1 term (6 months)
OWLv2 for Oxtoby/Gillis/Butler's Principles of Modern Chemistry, 8th Edition, [Instant Access], 1 term (6 months)
8th Edition
ISBN: 9781305271593
Author: David W. Oxtoby; H. Pat Gillis; Laurie J. Butler
Publisher: Cengage Learning US
Question
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Chapter 7, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The structural formula of 2,3-Dimethylpentane should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

Rules of drawing structures of alkanes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(b)

Interpretation Introduction

Interpretation:

The structural formula of 3-Ethyl-2-pentene should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Unsaturated hydrocarbon having one or more double bond is known as alkene having general molecular formula CnH2n .

Rules of drawing structures of alkenes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(c)

Interpretation Introduction

Interpretation:

The structural formula of Methylcyclopropane should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n .

Rules of drawing structures of cycloalkanes are:

  1. First identify the base name, and then draw the cyclic ring of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(d)

Interpretation Introduction

Interpretation:

The structural formula of 2,2-Dimethylbutane should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

Rules of drawing structures of alkanes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(e)

Interpretation Introduction

Interpretation:

The structural formula of 3-Propyl-2-hexene should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Unsaturated hydrocarbon having one or more double bond is known as alkene having general molecular formula CnH2n .

Rules of drawing structures of alkenes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(f)

Interpretation Introduction

Interpretation:

The structural formula of 3-Methyl-1-hexene should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Unsaturated hydrocarbon having one or more double bond is known as alkene having general molecular formula CnH2n .

Rules of drawing structures of alkenes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(g)

Interpretation Introduction

Interpretation:

The structural formula of 4-Ethyl-2-methylheptane should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

Rules of drawing structures of alkanes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

(h)

Interpretation Introduction

Interpretation:

The structural formula of 4-Ethyl-2-heptyne should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Unsaturated hydrocarbon with one or more triple bond is known as alkyne having general molecular formula CnH2n2 .

Rules of drawing structures of alkynes are:

  1. First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
  2. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Chapter 7 Solutions

OWLv2 for Oxtoby/Gillis/Butler's Principles of Modern Chemistry, 8th Edition, [Instant Access], 1 term (6 months)

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