Concept explainers
(a)
Interpretation:
The value of
Concept introduction:
The importance of
(a)
Answer to Problem 7F.9P
The value of
Explanation of Solution
The value of
Multiply the parentheses as shown below.
Hence, the value of
(b)
Interpretation:
The value of
Concept introduction:
The importance of angular momentum is comparable to the linear momentum in translational motion. In quantum mechanics, commutator of two operators tells the measurement of two operators at a same time. The commutator of angular momentum in two different axes is calculated by the formula shown below.
(b)
Answer to Problem 7F.9P
The value of
Explanation of Solution
The value of
Multiply the parentheses as shown below.
Hence, the value of
(c)
Interpretation:
The value of
Concept introduction:
The importance of angular momentum is comparable to the linear momentum in translational motion. In quantum mechanics, commutator of two operators tells the measurement of two operators at a same time. The commutator of angular momentum in two different axes is calculated by the formula shown below.
(c)
Answer to Problem 7F.9P
It has been proved that the value of
Explanation of Solution
The value of
Further solve the above equation, by multiplying and dividing by
Hence, it has been proved that the value of
(d)
Interpretation:
The cyclic permutation order for linear momentum operators has to be proved.
Concept introduction:
The importance of angular momentum is comparable to the linear momentum in translational motion. In quantum mechanics, commutator of two operators tells the measurement of two operators at a same time. The commutator of angular momentum in two different axes is calculated by the formula shown below.
(d)
Answer to Problem 7F.9P
It has been proved that linear momentum operators follow the cyclic permutation order.
Explanation of Solution
The
The
The
From equation (1), it is clear that the
(e)
Interpretation:
The commutations of other two angular momentum operators, by following the cyclic order permutation have to be predicted.
Concept introduction:
The importance of angular momentum is comparable to the linear momentum in translational motion. In quantum mechanics, commutator of two operators tells the measurement of two operators at a same time. The commutator of angular momentum in two different axes is calculated by the formula shown below.
(e)
Answer to Problem 7F.9P
The value of the commutation of
The value of the commutation of
Explanation of Solution
The value of the commutation of
By following the cyclic order permutation, the value of the commutation of
Similarly, the value of the commutation of
This proves that the commutations of other two angular momentum operators follow cyclic permutation order.
Want to see more full solutions like this?
Chapter 7 Solutions
ATKINS' PHYSICAL CHEMISTRY
- 4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).arrow_forwardThe emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forwardSteps and explanation pleasearrow_forward
- Try: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forwardNonearrow_forward16. Consider the probability distribution p(x) = ax", 0 ≤ x ≤ 1 for a positive integer n. A. Derive an expression for the constant a, to normalize p(x). B. Compute the average (x) as a function of n. C. Compute σ2 = (x²) - (x)², the variance of x, as a function of n.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY