ATKINS' PHYSICAL CHEMISTRY
ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
bartleby

Concept explainers

Question
Book Icon
Chapter 7, Problem 7D.7P

(a)

Interpretation Introduction

Interpretation:

The expression for Δx and Δpx for a particle of mass m in a one dimensional box of length L has to be calculated.

Concept introduction:

The wave function represents the exact position of the electron in an atom.  For a wave function to be acceptable, it must be normalized.  The wave function is represented by ψ in the quantum mechanics.  The normalized wavefunction of a particle of mass m in a one dimensional box of length L for a general quantum state n is shown below.

    ψ=(2L)1/2sin(nπx/L)

(b)

Interpretation Introduction

Interpretation:

The expression for the product of ΔxΔpx for a particle of mass m in a one dimensional box of length L has to be calculated.

Concept introduction:

The wave function represents the exact position of the electron in an atom.  For a wave function to be acceptable, it must be normalized.  The wave function is represented by ψ in the quantum mechanics.  The normalized wavefunction of a particle of mass m in a one dimensional box of length L for a general quantum state n is shown below.

    ψ=(2L)1/2sin(nπx/L)

(c)

Interpretation Introduction

Interpretation:

The validation of Heisenberg’s uncertainty principle for n=1,n=2 and also for n1 has to be shown.

Concept introduction:

Heisenberg’s uncertainty principle states that for a microscopic particle, there is always some uncertainty present in the measurement of the uncertainty in momentum and the uncertainty in the position of a particle simultaneously.  Heisenberg’s uncertainty principle can be proved indirectly by showing the result of the product of ΔxΔpx a positive quantity.

Blurred answer
Students have asked these similar questions
יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5
2H2S(g)+3O2(g)→2SO2(g)+2H2O(g) A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion. Question   Which of the following predicts the theoretical yield of SO2(g) from the reaction?     Responses 1.2 g Answer A: 1.2 grams A 41 g Answer B: 41 grams B 77 g Answer C: 77 grams C 154 g Answer D: 154 grams D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Chapter 7 Solutions

ATKINS' PHYSICAL CHEMISTRY

Ch. 7 - Prob. 7D.1STCh. 7 - Prob. 7E.1STCh. 7 - Prob. 7E.2STCh. 7 - Prob. 7F.1STCh. 7 - Prob. 7A.1DQCh. 7 - Prob. 7A.2DQCh. 7 - Prob. 7A.3DQCh. 7 - Prob. 7A.4DQCh. 7 - Prob. 7A.1AECh. 7 - Prob. 7A.1BECh. 7 - Prob. 7A.2AECh. 7 - Prob. 7A.2BECh. 7 - Prob. 7A.3AECh. 7 - Prob. 7A.3BECh. 7 - Prob. 7A.4AECh. 7 - Prob. 7A.4BECh. 7 - Prob. 7A.5AECh. 7 - Prob. 7A.5BECh. 7 - Prob. 7A.6AECh. 7 - Prob. 7A.6BECh. 7 - Prob. 7A.7AECh. 7 - Prob. 7A.7BECh. 7 - Prob. 7A.8AECh. 7 - Prob. 7A.8BECh. 7 - Prob. 7A.9AECh. 7 - Prob. 7A.9BECh. 7 - Prob. 7A.10AECh. 7 - Prob. 7A.10BECh. 7 - Prob. 7A.11AECh. 7 - Prob. 7A.11BECh. 7 - Prob. 7A.12AECh. 7 - Prob. 7A.12BECh. 7 - Prob. 7A.13AECh. 7 - Prob. 7A.13BECh. 7 - Prob. 7A.1PCh. 7 - Prob. 7A.2PCh. 7 - Prob. 7A.3PCh. 7 - Prob. 7A.4PCh. 7 - Prob. 7A.5PCh. 7 - Prob. 7A.6PCh. 7 - Prob. 7A.7PCh. 7 - Prob. 7A.8PCh. 7 - Prob. 7A.9PCh. 7 - Prob. 7A.10PCh. 7 - Prob. 7B.1DQCh. 7 - Prob. 7B.2DQCh. 7 - Prob. 7B.3DQCh. 7 - Prob. 7B.1AECh. 7 - Prob. 7B.1BECh. 7 - Prob. 7B.2AECh. 7 - Prob. 7B.2BECh. 7 - Prob. 7B.3AECh. 7 - Prob. 7B.3BECh. 7 - Prob. 7B.4AECh. 7 - Prob. 7B.4BECh. 7 - Prob. 7B.5AECh. 7 - Prob. 7B.5BECh. 7 - Prob. 7B.6AECh. 7 - Prob. 7B.6BECh. 7 - Prob. 7B.7AECh. 7 - Prob. 7B.7BECh. 7 - Prob. 7B.8AECh. 7 - Prob. 7B.8BECh. 7 - Prob. 7B.1PCh. 7 - Prob. 7B.2PCh. 7 - Prob. 7B.3PCh. 7 - Prob. 7B.4PCh. 7 - Prob. 7B.5PCh. 7 - Prob. 7B.7PCh. 7 - Prob. 7B.8PCh. 7 - Prob. 7B.9PCh. 7 - Prob. 7B.11PCh. 7 - Prob. 7C.1DQCh. 7 - Prob. 7C.2DQCh. 7 - Prob. 7C.3DQCh. 7 - Prob. 7C.1AECh. 7 - Prob. 7C.1BECh. 7 - Prob. 7C.2AECh. 7 - Prob. 7C.2BECh. 7 - Prob. 7C.3AECh. 7 - Prob. 7C.3BECh. 7 - Prob. 7C.4AECh. 7 - Prob. 7C.4BECh. 7 - Prob. 7C.5AECh. 7 - Prob. 7C.5BECh. 7 - Prob. 7C.6AECh. 7 - Prob. 7C.6BECh. 7 - Prob. 7C.7AECh. 7 - Prob. 7C.7BECh. 7 - Prob. 7C.8AECh. 7 - Prob. 7C.8BECh. 7 - Prob. 7C.9AECh. 7 - Prob. 7C.9BECh. 7 - Prob. 7C.10AECh. 7 - Prob. 7C.10BECh. 7 - Prob. 7C.1PCh. 7 - Prob. 7C.2PCh. 7 - Prob. 7C.3PCh. 7 - Prob. 7C.4PCh. 7 - Prob. 7C.5PCh. 7 - Prob. 7C.6PCh. 7 - Prob. 7C.7PCh. 7 - Prob. 7C.8PCh. 7 - Prob. 7C.9PCh. 7 - Prob. 7C.11PCh. 7 - Prob. 7C.12PCh. 7 - Prob. 7C.13PCh. 7 - Prob. 7C.14PCh. 7 - Prob. 7C.15PCh. 7 - Prob. 7D.1DQCh. 7 - Prob. 7D.2DQCh. 7 - Prob. 7D.3DQCh. 7 - Prob. 7D.1AECh. 7 - Prob. 7D.1BECh. 7 - Prob. 7D.2AECh. 7 - Prob. 7D.2BECh. 7 - Prob. 7D.3AECh. 7 - Prob. 7D.3BECh. 7 - Prob. 7D.4AECh. 7 - Prob. 7D.4BECh. 7 - Prob. 7D.5AECh. 7 - Prob. 7D.5BECh. 7 - Prob. 7D.6AECh. 7 - Prob. 7D.6BECh. 7 - Prob. 7D.7AECh. 7 - Prob. 7D.7BECh. 7 - Prob. 7D.8AECh. 7 - Prob. 7D.8BECh. 7 - Prob. 7D.9AECh. 7 - Prob. 7D.9BECh. 7 - Prob. 7D.10AECh. 7 - Prob. 7D.10BECh. 7 - Prob. 7D.11AECh. 7 - Prob. 7D.11BECh. 7 - Prob. 7D.12AECh. 7 - Prob. 7D.12BECh. 7 - Prob. 7D.13AECh. 7 - Prob. 7D.13BECh. 7 - Prob. 7D.14AECh. 7 - Prob. 7D.14BECh. 7 - Prob. 7D.15AECh. 7 - Prob. 7D.15BECh. 7 - Prob. 7D.1PCh. 7 - Prob. 7D.2PCh. 7 - Prob. 7D.3PCh. 7 - Prob. 7D.4PCh. 7 - Prob. 7D.5PCh. 7 - Prob. 7D.6PCh. 7 - Prob. 7D.7PCh. 7 - Prob. 7D.8PCh. 7 - Prob. 7D.9PCh. 7 - Prob. 7D.11PCh. 7 - Prob. 7D.12PCh. 7 - Prob. 7D.14PCh. 7 - Prob. 7E.1DQCh. 7 - Prob. 7E.2DQCh. 7 - Prob. 7E.3DQCh. 7 - Prob. 7E.1AECh. 7 - Prob. 7E.1BECh. 7 - Prob. 7E.2AECh. 7 - Prob. 7E.2BECh. 7 - Prob. 7E.3AECh. 7 - Prob. 7E.3BECh. 7 - Prob. 7E.4AECh. 7 - Prob. 7E.4BECh. 7 - Prob. 7E.5AECh. 7 - Prob. 7E.5BECh. 7 - Prob. 7E.6AECh. 7 - Prob. 7E.6BECh. 7 - Prob. 7E.7AECh. 7 - Prob. 7E.7BECh. 7 - Prob. 7E.8AECh. 7 - Prob. 7E.8BECh. 7 - Prob. 7E.9AECh. 7 - Prob. 7E.9BECh. 7 - Prob. 7E.1PCh. 7 - Prob. 7E.2PCh. 7 - Prob. 7E.3PCh. 7 - Prob. 7E.4PCh. 7 - Prob. 7E.5PCh. 7 - Prob. 7E.6PCh. 7 - Prob. 7E.7PCh. 7 - Prob. 7E.8PCh. 7 - Prob. 7E.9PCh. 7 - Prob. 7E.12PCh. 7 - Prob. 7E.15PCh. 7 - Prob. 7E.16PCh. 7 - Prob. 7E.17PCh. 7 - Prob. 7F.1DQCh. 7 - Prob. 7F.2DQCh. 7 - Prob. 7F.3DQCh. 7 - Prob. 7F.1AECh. 7 - Prob. 7F.1BECh. 7 - Prob. 7F.2AECh. 7 - Prob. 7F.2BECh. 7 - Prob. 7F.3AECh. 7 - Prob. 7F.3BECh. 7 - Prob. 7F.4AECh. 7 - Prob. 7F.4BECh. 7 - Prob. 7F.5AECh. 7 - Prob. 7F.5BECh. 7 - Prob. 7F.6AECh. 7 - Prob. 7F.6BECh. 7 - Prob. 7F.7AECh. 7 - Prob. 7F.7BECh. 7 - Prob. 7F.8AECh. 7 - Prob. 7F.8BECh. 7 - Prob. 7F.9AECh. 7 - Prob. 7F.9BECh. 7 - Prob. 7F.10AECh. 7 - Prob. 7F.10BECh. 7 - Prob. 7F.11AECh. 7 - Prob. 7F.11BECh. 7 - Prob. 7F.12AECh. 7 - Prob. 7F.12BECh. 7 - Prob. 7F.13AECh. 7 - Prob. 7F.13BECh. 7 - Prob. 7F.14AECh. 7 - Prob. 7F.14BECh. 7 - Prob. 7F.1PCh. 7 - Prob. 7F.4PCh. 7 - Prob. 7F.6PCh. 7 - Prob. 7F.7PCh. 7 - Prob. 7F.8PCh. 7 - Prob. 7F.9PCh. 7 - Prob. 7F.10PCh. 7 - Prob. 7F.11PCh. 7 - Prob. 7.3IACh. 7 - Prob. 7.4IACh. 7 - Prob. 7.5IACh. 7 - Prob. 7.6IA
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY