The reaction of a metal, M, with a halogen, X 2 , proceeds by an exothermic reaction as indicated by this equation: M ( s ) + X 2 ( g ) → MX 2 ( s ) . For each of the following, indicate which option will make the reaction more exothermic. Explain your answers. (a) a large radius vs. a small radius for M + 2 (b) a high ionization energy vs. a low ionization energy for M (c) an increasing bond energy for the halogen (d) a decreasing electron affinity for the halogen (e) an increasing size of the anion formed by the halogen
The reaction of a metal, M, with a halogen, X 2 , proceeds by an exothermic reaction as indicated by this equation: M ( s ) + X 2 ( g ) → MX 2 ( s ) . For each of the following, indicate which option will make the reaction more exothermic. Explain your answers. (a) a large radius vs. a small radius for M + 2 (b) a high ionization energy vs. a low ionization energy for M (c) an increasing bond energy for the halogen (d) a decreasing electron affinity for the halogen (e) an increasing size of the anion formed by the halogen
The reaction of a metal, M, with a halogen,
X
2
, proceeds by an exothermic reaction as indicated by this equation:
M
(
s
)
+
X
2
(
g
)
→
MX
2
(
s
)
. For each of the following, indicate which option will make the reaction more exothermic. Explain your answers.
(a) a large radius vs. a small radius for
M
+
2
(b) a high ionization energy vs. a low ionization energy for M
(c) an increasing bond energy for the halogen
(d) a decreasing electron affinity for the halogen
(e) an increasing size of the anion formed by the halogen
Definition Definition Change in energy of a neutral gaseous atom when an electron is added to the atom to form a negative ion.
Last Name, Firs
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
• 6H total $ 4th total
21 total
4H total
ZH
2H
Statistical
H < 3°C-H werkst
-
product
bund abstraction here
leads to the mo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Proclict
6
Number of Unique
Mono-Chlorinated Products
f
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
'H
H-Cl
Waterfox
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
I find the solution way too brief and unsatisfactory as it does not clearly explain the solution provided in the problem.
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell