Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
7th Edition
ISBN: 9781305081086
Author: STOKER, H. Stephen
Publisher: Brooks Cole
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Question
Chapter 7, Problem 7.79EP
(a)
Interpretation Introduction
Interpretation:
The given statement “for systems in a state of physical equilibrium, two opposite processes take place at equal rates” is true or false has to be indicated.
Concept Introduction:
Physical equilibrium is a state in which two physical processes which are opposing to each other takes place at the same rate at this moment there is no net macroscopic changes can be happened but system is dynamic and at equal rate the forward and reverse process are occurred.
(b)
Interpretation Introduction
Interpretation:
The given statement “a liquid-vapor equilibrium situation is an example of a physical equilibrium state” is true or false has to be indicated.
Concept Introduction:
Physical equilibrium is a state in which two physical processes which are opposing to each other takes place at the same rate at this moment there is no net macroscopic changes can be happened but system is dynamic and at equal rate the forward and reverse process are occurred.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
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Chapter 7 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
Ch. 7.1 - Prob. 1QQCh. 7.1 - Prob. 2QQCh. 7.1 - Prob. 3QQCh. 7.2 - Prob. 1QQCh. 7.2 - Prob. 2QQCh. 7.2 - Prob. 3QQCh. 7.3 - Prob. 1QQCh. 7.3 - Prob. 2QQCh. 7.3 - Prob. 3QQCh. 7.4 - Prob. 1QQ
Ch. 7.4 - Prob. 2QQCh. 7.4 - Based on Boyles law, if the pressure on 30.0 mL of...Ch. 7.5 - Prob. 1QQCh. 7.5 - Prob. 2QQCh. 7.5 - Prob. 3QQCh. 7.6 - Prob. 1QQCh. 7.6 - Prob. 2QQCh. 7.6 - Prob. 3QQCh. 7.7 - Prob. 1QQCh. 7.7 - Prob. 2QQCh. 7.7 - Prob. 3QQCh. 7.7 - Prob. 4QQCh. 7.8 - Prob. 1QQCh. 7.8 - Prob. 2QQCh. 7.8 - Prob. 3QQCh. 7.9 - Prob. 1QQCh. 7.9 - Prob. 2QQCh. 7.9 - Prob. 3QQCh. 7.10 - Prob. 1QQCh. 7.10 - Prob. 2QQCh. 7.10 - Prob. 3QQCh. 7.11 - Prob. 1QQCh. 7.11 - Prob. 2QQCh. 7.11 - Prob. 3QQCh. 7.11 - Prob. 4QQCh. 7.11 - Prob. 5QQCh. 7.11 - Prob. 6QQCh. 7.12 - Prob. 1QQCh. 7.12 - Prob. 2QQCh. 7.12 - Prob. 3QQCh. 7.13 - Prob. 1QQCh. 7.13 - Prob. 2QQCh. 7.13 - Prob. 3QQCh. 7.13 - Prob. 4QQCh. 7.13 - Prob. 5QQCh. 7.13 - Prob. 6QQCh. 7 - Indicate whether each of the following statements...Ch. 7 - Indicate whether each of the following statements...Ch. 7 - Prob. 7.3EPCh. 7 - Prob. 7.4EPCh. 7 - Prob. 7.5EPCh. 7 - Prob. 7.6EPCh. 7 - Prob. 7.7EPCh. 7 - Prob. 7.8EPCh. 7 - Prob. 7.9EPCh. 7 - Prob. 7.10EPCh. 7 - Prob. 7.11EPCh. 7 - Prob. 7.12EPCh. 7 - Prob. 7.13EPCh. 7 - Prob. 7.14EPCh. 7 - Prob. 7.15EPCh. 7 - Prob. 7.16EPCh. 7 - Prob. 7.17EPCh. 7 - Prob. 7.18EPCh. 7 - A sample of ammonia (NH3), a colorless gas with a...Ch. 7 - A sample of nitrogen dioxide (NO2), a toxic gas...Ch. 7 - Prob. 7.21EPCh. 7 - Prob. 7.22EPCh. 7 - Prob. 7.23EPCh. 7 - Prob. 7.24EPCh. 7 - Prob. 7.25EPCh. 7 - Prob. 7.26EPCh. 7 - A sample of N2 gas occupies a volume of 375 mL at...Ch. 7 - A sample of Ar gas occupies a volume of 1.2 L at...Ch. 7 - Prob. 7.29EPCh. 7 - Prob. 7.30EPCh. 7 - Prob. 7.31EPCh. 7 - Prob. 7.32EPCh. 7 - Prob. 7.33EPCh. 7 - Prob. 7.34EPCh. 7 - Prob. 7.35EPCh. 7 - Prob. 7.36EPCh. 7 - Prob. 7.37EPCh. 7 - Prob. 7.38EPCh. 7 - Prob. 7.39EPCh. 7 - Prob. 7.40EPCh. 7 - Prob. 7.41EPCh. 7 - Prob. 7.42EPCh. 7 - Prob. 7.43EPCh. 7 - Prob. 7.44EPCh. 7 - Prob. 7.45EPCh. 7 - Prob. 7.46EPCh. 7 - Prob. 7.47EPCh. 7 - Prob. 7.48EPCh. 7 - Prob. 7.49EPCh. 7 - Prob. 7.50EPCh. 7 - Determine the following for a 0.250-mole sample of...Ch. 7 - Determine the following for a 0.500-mole sample of...Ch. 7 - Prob. 7.53EPCh. 7 - Prob. 7.54EPCh. 7 - Prob. 7.55EPCh. 7 - What is the value of the ideal gas constant R if...Ch. 7 - The total pressure exerted by a mixture of O2, N2,...Ch. 7 - The total pressure exerted by a mixture of He, Ne,...Ch. 7 - A gas mixture contains O2, N2, and Ar at partial...Ch. 7 - A gas mixture contains He, Ne, and H2S at partial...Ch. 7 - Prob. 7.61EPCh. 7 - Prob. 7.62EPCh. 7 - Prob. 7.63EPCh. 7 - Prob. 7.64EPCh. 7 - Prob. 7.65EPCh. 7 - Prob. 7.66EPCh. 7 - Prob. 7.67EPCh. 7 - Prob. 7.68EPCh. 7 - Prob. 7.69EPCh. 7 - Prob. 7.70EPCh. 7 - Prob. 7.71EPCh. 7 - Prob. 7.72EPCh. 7 - What are the two ways in which the escape of...Ch. 7 - Prob. 7.74EPCh. 7 - Prob. 7.75EPCh. 7 - How does an increase in the surface area of a...Ch. 7 - Prob. 7.77EPCh. 7 - Prob. 7.78EPCh. 7 - Prob. 7.79EPCh. 7 - Prob. 7.80EPCh. 7 - Prob. 7.81EPCh. 7 - What is the relationship between the strength of...Ch. 7 - What term is used to describe a substance that...Ch. 7 - Prob. 7.84EPCh. 7 - Indicate whether each of the following statements...Ch. 7 - Indicate whether each of the following statements...Ch. 7 - Prob. 7.87EPCh. 7 - What is the relationship between location...Ch. 7 - Prob. 7.89EPCh. 7 - Prob. 7.90EPCh. 7 - Indicate whether or not each of the following...Ch. 7 - Prob. 7.92EPCh. 7 - Prob. 7.93EPCh. 7 - Prob. 7.94EPCh. 7 - For liquid-state samples of the following diatomic...Ch. 7 - For liquid-state samples of the following diatomic...Ch. 7 - Prob. 7.97EPCh. 7 - Prob. 7.98EPCh. 7 - Prob. 7.99EPCh. 7 - Prob. 7.100EPCh. 7 - Prob. 7.101EPCh. 7 - Prob. 7.102EPCh. 7 - Prob. 7.103EPCh. 7 - Prob. 7.104EPCh. 7 - Prob. 7.105EPCh. 7 - Prob. 7.106EP
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