EBK LABORATORY MANUAL FOR GENERAL, ORGA
3rd Edition
ISBN: 9780100668324
Author: Timberlake
Publisher: YUZU
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Chapter 7, Problem 7.73AP
Summary Introduction
To explain:
Why straight chain
Introduction:
The pressure of a vapor in contact with its liquid or solid from called vapor pressure. Straight chain alkane has a lower vapor pressure as compare to branched chain alkane even with same molecular formula it is because vapor pressure is temperature dependent, higher boiling point means lower vapor pressure, because it will take more energy to vaporize, it also depend on the attractive forces and in the surface area of the molecule.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 7 Solutions
EBK LABORATORY MANUAL FOR GENERAL, ORGA
Ch. 7 - Prob. 7.1PPCh. 7 - Prob. 7.2PPCh. 7 - Prob. 7.3PPCh. 7 - Given that only polar molecules can participate as...Ch. 7 - Prob. 7.5PPCh. 7 - Prob. 7.6PPCh. 7 - An ion-dipole attraction often occurs when ionic...Ch. 7 - Prob. 7.8PPCh. 7 - Prob. 7.9PPCh. 7 - Prob. 7.10PP
Ch. 7 - Prob. 7.11PPCh. 7 - Prob. 7.12PPCh. 7 - Prob. 7.13PPCh. 7 - Prob. 7.14PPCh. 7 - Prob. 7.15PPCh. 7 - Prob. 7.16PPCh. 7 - Prob. 7.17PPCh. 7 - Prob. 7.18PPCh. 7 - Nitrous oxide, N2O, or laughing gas, is a common...Ch. 7 - An Ambu bag is used in emergency resuscitation....Ch. 7 - Prob. 7.21PPCh. 7 - Prob. 7.22PPCh. 7 - Prob. 7.23PPCh. 7 - As a cylinder of compressed gas empties, the...Ch. 7 - Prob. 7.25PPCh. 7 - Prob. 7.26PPCh. 7 - Prob. 7.27PPCh. 7 - Prob. 7.28PPCh. 7 - Prob. 7.29PPCh. 7 - Prob. 7.30PPCh. 7 - Prob. 7.31PPCh. 7 - Prob. 7.32PPCh. 7 - Prob. 7.33PPCh. 7 - Prob. 7.34PPCh. 7 - Prob. 7.35PPCh. 7 - What component molecules make up a triglyceride?Ch. 7 - Prob. 7.37PPCh. 7 - Prob. 7.38PPCh. 7 - Prob. 7.39PPCh. 7 - Prob. 7.40PPCh. 7 - Prob. 7.41PPCh. 7 - Prob. 7.42PPCh. 7 - Prob. 7.43APCh. 7 - Prob. 7.44APCh. 7 - Prob. 7.45APCh. 7 - Prob. 7.46APCh. 7 - Prob. 7.47APCh. 7 - Prob. 7.48APCh. 7 - Prob. 7.49APCh. 7 - Prob. 7.50APCh. 7 - Prob. 7.51APCh. 7 - Prob. 7.52APCh. 7 - Prob. 7.53APCh. 7 - Prob. 7.54APCh. 7 - A beach ball is filled with 10.0 L of air in a...Ch. 7 - Prob. 7.56APCh. 7 - Prob. 7.57APCh. 7 - Liquid nitrogen is an extremely cold liquid (196...Ch. 7 - A full cylinder of compressed gas is moved to a...Ch. 7 - Prob. 7.60APCh. 7 - Your friend breathes in 1.5 L of helium from a...Ch. 7 - Prob. 7.62APCh. 7 - Prob. 7.63APCh. 7 - Prob. 7.64APCh. 7 - Predict which member of each of the following...Ch. 7 - Predict which member of each of the following...Ch. 7 - A stain on your shirt will not come out when you...Ch. 7 - Prob. 7.68APCh. 7 - Prob. 7.69APCh. 7 - Prob. 7.70APCh. 7 - Prob. 7.71APCh. 7 - Prob. 7.72APCh. 7 - Prob. 7.73APCh. 7 - Prob. 7.74APCh. 7 - Prob. 7.75APCh. 7 - Prob. 7.76APCh. 7 - Prob. 7.77APCh. 7 - Prob. 7.78APCh. 7 - Prob. 7.79APCh. 7 - Soap, phospholipids, and cholesterol are all...Ch. 7 - Describe other components present in a cell...Ch. 7 - Prob. 7.82APCh. 7 - Prob. 7.83CPCh. 7 - Desflurane and sevoflurane are common inhalation...Ch. 7 - Prob. 7.85CPCh. 7 - Prob. 7.86CPCh. 7 - Prob. 7.87CPCh. 7 - Getem Clean, Inc. has hired you as chief chcmnt...Ch. 7 - Prob. 7.89CPCh. 7 - Prob. 1IA.1QCh. 7 - Prob. 1IA.2QCh. 7 - Prob. 1IA.3QCh. 7 - Prob. 1IA.4QCh. 7 - Prob. 1IA.5QCh. 7 - Prob. 1IA.6QCh. 7 - Prob. 1IA.7QCh. 7 - Prob. 2IA.1QCh. 7 - Prob. 2IA.2QCh. 7 - Prob. 2IA.3QCh. 7 - Prob. 2IA.4QCh. 7 - Prob. 2IA.5QCh. 7 - Prob. 2IA.6QCh. 7 - Prob. 2IA.7QCh. 7 - Devise a rule to predict the solubility of an...Ch. 7 - Prob. 1ICCh. 7 - Prob. 2ICCh. 7 - Prob. 3IC
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