CHEMISTRY:MOLECULAR...V.2 W/ACCESS
CHEMISTRY:MOLECULAR...V.2 W/ACCESS
9th Edition
ISBN: 9781265927103
Author: SILBERBERG
Publisher: MCG CUSTOM
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Quantum Chemistry
Quantum chemistry deals with the properties of chemical systems and their reactions. The branch of chemistry which is more concerned with quantum chemistry is physical chemistry. It is a more sophisticated field of theoretical physics which is concerned …
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Chapter 7, Problem 7.72P

(a)

Interpretation Introduction

Interpretation:

The correct l value for the combination n=3;l=0;ml=−1 is to be determined.

Concept introduction:

Quantum numbers are a set of four numbers that gives complete information about an electron within an atom. Out of the four, the three quantum numbers that define the shape, size, and orientation of an orbital are the principal quantum number, the orbital angular momentum quantum number, and the magnetic quantum number.

The formula to calculate the highest possible value of angular momentum quantum number l for a given value of a principal quantum number n is as follows:

Highest value for l=n−1        (1)

(b)

Interpretation Introduction

Interpretation:

The correct l value for the combination n=3;l=3;ml=+1 is to be determined.

Concept introduction:

Quantum numbers are a set of four numbers that gives complete information about an electron within an atom. Out of the four, the three quantum numbers that define the shape, size, and orientation of an orbital are the principal quantum number, the orbital angular momentum quantum number, and the magnetic quantum number.

The formula to determine the total number of orbitals is,

Number of orbitals=2l+1        (1)

(c)

Interpretation Introduction

Interpretation:

The correct l value for the combination n=7;l=2;ml=+3 is to be determined.

Concept introduction:

Quantum numbers are a set of four numbers that gives complete information about an electron within an atom. Out of the four, the three quantum numbers that define the shape, size, and orientation of an orbital are the principal quantum number, the orbital angular momentum quantum number, and the magnetic quantum number.

The formula to determine the total number of orbitals is,

Number of orbitals=2l+1        (1)

(d)

Interpretation Introduction

Interpretation:

The correct l value for the combination n=4;l=1;ml=−2 is to be determined.

Concept introduction:

Quantum numbers are a set of four numbers that gives complete information about an electron within an atom. Out of the four, the three quantum numbers that define the shape, size, and orientation of an orbital are the principal quantum number, the orbital angular momentum quantum number, and the magnetic quantum number.

The formula to determine the total number of orbitals is,

Number of orbitals=2l+1        (1)

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Chapter 7 Solutions

CHEMISTRY:MOLECULAR...V.2 W/ACCESS

Ch. 7.1 - Some diamonds appear yellow because they contain...Ch. 7.1 - Prob. 7.1BFPCh. 7.1 - Prob. 7.2AFPCh. 7.1 - Prob. 7.2BFPCh. 7.2 - Prob. 7.3AFPCh. 7.2 - Prob. 7.3BFPCh. 7.3 - Prob. 7.4AFPCh. 7.3 - Prob. 7.4BFPCh. 7.3 - Prob. 7.5AFPCh. 7.3 - Prob. 7.5BFP
Ch. 7.4 - Prob. 7.6AFPCh. 7.4 - Prob. 7.6BFPCh. 7.4 - Prob. 7.7AFPCh. 7.4 - Prob. 7.7BFPCh. 7.4 - Prob. 7.8AFPCh. 7.4 - Prob. 7.8BFPCh. 7 - Prob. 7.1PCh. 7 - Consider the following types of electromagnetic...Ch. 7 - Prob. 7.3PCh. 7 - In the 17th century, Isaac Newton proposed that...Ch. 7 - Prob. 7.5PCh. 7 - What new idea about light did Einstein use to...Ch. 7 - An AM station broadcasts rock music at “950 on...Ch. 7 - An FM station broadcasts music at 93.5 MHz...Ch. 7 - Prob. 7.9PCh. 7 - An x-ray has a wavelength of 1.3 Å. Calculate the...Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Police often monitor traffic with “K-band” radar...Ch. 7 - Covalent bonds in a molecule absorb radiation in...Ch. 7 - Prob. 7.15PCh. 7 - Prob. 7.16PCh. 7 - How is n1 in the Rydberg equation (Equation 7.4)...Ch. 7 - What key assumption of Bohr’s model would a “Solar...Ch. 7 - Prob. 7.19PCh. 7 - Which of these electron transitions correspond to...Ch. 7 - Why couldn’t the Bohr model predict spectra for...Ch. 7 - Prob. 7.22PCh. 7 - Use the Rydberg equation to find the wavelength...Ch. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Prob. 7.31PCh. 7 - Prob. 7.32PCh. 7 - In addition to continuous radiation, fluorescent...Ch. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - A 232-lb fullback runs 40 yd at 19.8 ± 0.1...Ch. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Prob. 7.42PCh. 7 - Prob. 7.43PCh. 7 - Prob. 7.44PCh. 7 - What physical meaning is attributed to ψ2? Ch. 7 - What does “electron density in a tiny volume of...Ch. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - How many orbitals in an atom can have each of the...Ch. 7 - Prob. 7.50PCh. 7 - Give all possible ml values for orbitals that have...Ch. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - The quantum-mechanical treatment of the H atom...Ch. 7 - The photoelectric effect is illustrated in a plot...Ch. 7 - Prob. 7.64PCh. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - Prob. 7.69PCh. 7 - Prob. 7.70PCh. 7 - Prob. 7.71PCh. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Use the relative size of the 3s orbital below to...Ch. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Enormous numbers of microwave photons are needed...Ch. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - Prob. 7.82PCh. 7 - Prob. 7.83PCh. 7 - Prob. 7.84PCh. 7 - For any microscope, the size of the smallest...Ch. 7 - In fireworks, the heat of the reaction of an...Ch. 7 - Prob. 7.87PCh. 7 - Fish-liver oil is a good source of vitamin A,...Ch. 7 - Many calculators use photocells as their energy...Ch. 7 - Prob. 7.90PCh. 7 - Prob. 7.91PCh. 7 - Prob. 7.92PCh. 7 - The flame tests for sodium and potassium are based...Ch. 7 - Prob. 7.94PCh. 7 - Prob. 7.95PCh. 7 - The discharge of phosphate in detergents to the...
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