(a) Interpretation: The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified. Concept introduction: Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

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Answer 1

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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Answer 3

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Expert Solution & Answer

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Answer 4

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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Answer 5

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Answer 6

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Answer 7

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Answer 10

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Answer 13

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

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