(a) Interpretation: The alkyl halide , from the given pair, that reacts faster in an S N 1 reaction is to be identified. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1 ° < 2 ° < 3 ° .

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Answer 1

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Q1: Predict the major organic product(s) of the following reactions. Include stereochemistry when necessary. Write NR if no reaction, try to explain. 1.) LDA, THF 2.) СОН CI OH H2SO4, heat OH m...... OH 1.) PCC, CH2Cl2 2.) CH3CH2MgBr, THF 3.) H3O+ 4.) TsCl, pyr 5.) tBuOK, tBuOH 1.) SOCI 2, CHCI 3 2.) CH3CH2ONA, DMF OH 1.) HBr 2.) Mg, THF 3.) H₂CO, THE 4.) H3O+ OH NaH, THF

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Draw the major product of this reaction

Answer 2

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Answer 3

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Answer 4

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Answer 5

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 6

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 7

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.3P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.5P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - What neutral nucleophile is needed to convert...Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that in unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound.

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