Physical Chemistry Plus Mastering Chemistry With Etext -- Access Card Package (3rd Edition) (engel Physical Chemistry Series)
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Chapter 7, Problem 7.25NP

(a)

Interpretation Introduction

Interpretation:

The value of Vc should be calculated assuming methane is an ideal gas.

Concept Introduction :

For an ideal gas,

  VC=RTCPC

  VC - critical volumeR - universal gas constantTC - critical temperaturePC - critical pressure

(b)

Interpretation Introduction

Interpretation:

The value of Vc should be calculated assuming methane is a van der Waals gas.

Concept Introduction :

For a van der Waals gas,

  zC=PCVCRTC=38

  zC - critical compression factorVC - critical volumeR - universal gas constantTC - critical temperaturePC - critical pressure

(c)

Interpretation Introduction

Interpretation:

The value of Vc should be calculated assuming methane is a Redlich-Kwong gas.

Concept Introduction :

For a Redlich-Kwong gas,

  zC=PCVCRTC=0.333

Here,

  zC - critical compression factorVC - critical volumeR - universal gas constantTC - critical temperaturePC - critical pressure

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10:04 AM Tue Mar 25 Sunday 9:30 AM 95% Edit Draw the corresponding structures in each of the boxes below: Ester Name Methyl butyrate (Example) Alcohol Structure H3C-OH Acid Structure Ester Structure Isoamyl acetate Ethyl butyrate Propyl acetate Methyl salicylate Octyl acetate Isobutyl propionate Benzyl butyrate Benzyl acetate Ethyl acetate H₂C OH HC
2) For each of the following reactions: (i) (ii) Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word "racemic". (a) (b) 1) R₂BH 2) H₂O2, NaOH (aq) HBr Br racemic Br + Br Br racemic
For each of the following reactions:  Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word “racemic”.
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